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• 作者：Tian-Jiao Zhang ; Rui Pan ; Huan He ; Bai-Feng Yang ; Guo-Yu Yang
• 关键词：Borate ; Solvothermal synthesis ; Oxoboron cluster ; Structure
• 刊名：Journal of Cluster Science
• 出版年：2016
• 出版时间：March 2016
• 年：2016
• 卷：27
• 期：2
• 页码：625-633
• 全文大小：1,304 KB
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• 作者单位：Tian-Jiao Zhang (1)
  Rui Pan (1)
  Huan He (1)
  Bai-Feng Yang (1)
  Guo-Yu Yang (1)
  
  1. MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, Beijing, 100081, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Inorganic Chemistry
  Physical Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1572-8862

文摘

Two new metal borates, K[B₇O₉(OH)₅]·Hen (1, en = enthylenediamine) and Na₂Cs₄Ba₂[B₁₂O₁₈(OH)₆]·4(OH) (2) have been synthesized under solvothermal conditions. Their structures were determined by the single crystal X-ray diffraction and were further characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis and powder X-ray diffraction, respectively. 1 crystallizes in the triclinic system, P-1 space group, a = 7.7152(6), b = 8.4057(6), c = 12.1319(10) Å, α = 92.505(6), β = 98.944(7), γ = 103.825(6)°, Z = 2. 2 crystallizes in the orthorhombic system, Pmn2₁ space group, a = 12.6972(6) Å, b = 13.7037(6) Å, c = 9.4968(5) Å, Z = 2. Compound 1 consists of isolated [B₇O₉(OH)₅]2− clusters which are held together through H-bonding interactions and K atoms to form a 3-D supramolecular framework. For 2, bowl-like isolated [B₁₂O₁₈(OH)₆]6− clusters were linked together to form a 3-D framework by different metal ions and H-bond system.