Synthesis of tert-butyl acetate via eco-friendly additive reaction over mesoprous silica catalysts with balanced Brönsted and Lewis acid sites

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• 作者：Xian Chen ; Jingyuan Feng ; Zhaoyang Fei ; Wenjuan Sun…
• 关键词：Mesoporous silica materials ; Acid catalysis ; Acid balance ; Tert ; butyl acetate ; Additive reaction
• 刊名：Journal of Porous Materials
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：23
• 期：1
• 页码：255-262
• 全文大小：820 KB
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• 作者单位：Xian Chen (1)
  Jingyuan Feng (1)
  Zhaoyang Fei (1) (2)
  Wenjuan Sun (1)
  Jihai Tang (1)
  Pingping He (1)
  Mifen Cui (1)
  Xu Qiao (1) (2)
  
  1. College of Chemistry and Chemical Engineering, Nanjing Tech University, Nanjing, 210009, China
  2. State Key Laboratory of Materials Oriented Chemical Engineering, Nanjing Tech University, Nanjing, 210009, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Characterization and Evaluation Materials
  Physical Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1573-4854

文摘

The dual-modified SBA-15 materials (A–S–Si) with Al ions inserting in the framework and −SO₃H groups grafting on the pore wall were prepared via a co-condensation method and characterized by a series of techniques. The characterization results implied that the A–S–Si samples have typically mesoporous structure and different acid properties. The catalytic performance of A–S–Si catalysts in the additive reaction of acetic acid with isobutene was studied. The results showed that the conversion of acetic acid strongly depended on the Brönsted acidity, while the selectivity of tert-butyl acetate (TBAC) was linear correlated with the ratio of Brönsted and Lewis acid amounts. The conversion of acetic acid could reach 72 % with the selectivity of TBAC as high as 97 % over A₅–S₁₀–Si with balanced Brönsted and Lewis acid under the optimal conditions. An additional advantage was that the dual-modified catalyst can be recycled and regenerate with good stability. Keywords Mesoporous silica materials Acid catalysis Acid balance Tert-butyl acetate Additive reaction