Three-dimensional porous graphene sponges assembled with the combination of surfactant and freeze-drying
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- 作者：Rujing Zhang (1)
Yachang Cao (1)
Peixu Li (2)
Xiaobei Zang (1)
Pengzhan Sun (1)
Kunlin Wang (1)
Minlin Zhong (1)
Jinquan Wei (1)
Dehai Wu (2)
Feiyu Kang (1) (3)
Hongwei Zhu (1) (3) (4) - 关键词：graphene sponge ; hierarchical ; freezing media ; porous ; foams
- 刊名：Nano Research
- 出版年：2014
- 出版时间：October 2014
- 年：2014
- 卷：7
- 期：10
- 页码：1477-1487
- 全文大小：3,512 KB
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Yachang Cao (1)
Peixu Li (2)
Xiaobei Zang (1)
Pengzhan Sun (1)
Kunlin Wang (1)
Minlin Zhong (1)
Jinquan Wei (1)
Dehai Wu (2)
Feiyu Kang (1) (3)
Hongwei Zhu (1) (3) (4)
1. School of Materials Science and Engineering, State Key Laboratory of New Ceramics and Fine Processing, Key Laboratory of Materials Processing Technology of MOE, Tsinghua University, Beijing, 100084, China
2. Department of Mechanical Engineering, Tsinghua University, Beijing, 100084, China
3. Advanced Materials Institute, Graduate School at Shenzhen, Tsinghua University, Shenzhen, 518055, China
4. Center for Nano and Micro Mechanics, Tsinghua University, Beijing, 100084, China - ISSN：1998-0000
文摘
With the combination of surfactant and freeze-drying, we have developed two kinds of graphene spongy structures. On the one hand, using foams of soap bubbles as templates, three-dimensional porous graphene sponges with rich hierarchical pores have been synthesized. Pores of the material contain three levels of length scales, including millimeter, micrometer and nanometer. The structure can be tuned by changing the freezing media, adjusting the stirring rate or adding functional additives. On the other hand, by direct freeze-drying of a graphene oxide/surfactant suspension, a porous framework with directionally aligned pores is prepared. The surfactant gives a better dispersion of graphene oxide sheets, resulting in a high specific surface area. Both of the obtained materials exhibit excellent absorption capacity and good compression performance, providing a broad range of possible applications, such as absorbents, storage media, and carriers.