Energetic Al/Fe2O3/PVDF composites for high energy release: Importance of polymer binder and interface
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- 作者：Jae Hun Lee ; Sang Jin Kim ; Jung Soo Park ; Jong Hak Kim
- 关键词：reactive material ; aluminum (Al) ; iron oxide (Fe2O3) ; poly(vinylidene fluoride) (PVDF) ; energy release
- 刊名：Macromolecular Research
- 出版年：2016
- 出版时间：October 2016
- 年：2016
- 卷：24
- 期：10
- 页码：909-914
- 全文大小：2,130 KB
- 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Physical Chemistry
Polymer Sciences
Characterization and Evaluation of Materials
Soft and Granular Matter, Complex Fluids and Microfluidics
Nanochemistry
Nanotec - 出版者：The Polymer Society of Korea, co-published with Springer
- ISSN：2092-7673
- 卷排序：24
文摘
Energetic composite materials are very important in military purpose and building explosion but, the role of polymer binder and the materials interfaces has been little reported. Here, we prepared energetic composites consisting of aluminum (Al), iron oxide (Fe2O3) and polymer, as the fuel, oxidizer and binder, respectively. Two different methods, i.e. physical mixing and compression molding were employed to form blended powder and composite film, respectively. The use of partially fluorinated polymer such as poly(vinylidene fluoride) (PVDF) resulted in large improvement in exothermic energy compared to that of hydrocarbon polymer such as poly(vinyl pyrrolidone) (PVP), representing that fluorocarbon groups are actively involved in the reaction and PVDF acts as an oxidizer as well as binder. Furthermore, the Al/Fe2O3/PVDF film prepared by compression molding exhibited much higher exothermic energy than the blended powder, indicating the importance of intimate contact property of energetic materials for energy release.Keywordsreactive materialaluminum (Al)iron oxide (Fe2O3)poly(vinylidene fluoride) (PVDF)energy releaseReferences(1).N. Degirmenbasi, S. Coskun, N. Boz, and D. M. Kalyon, Fuel, 153, 620 (2015).CrossRefGoogle Scholar(2).Y.-R. Huang, Y. Jiang, J. L. Hor, R. Gupta, L. Zhang, K. J. Stebe, G. Feng, K. T. Turner, and D. Lee, Nanoscale, 7, 798 (2015).CrossRefGoogle Scholar(3).J. T. Park, W. S. Chi, D. K. Roh, S. H. Ahn, and J. H. Kim, Adv. Funct. Mater., 23, 26 (2013).CrossRefGoogle Scholar(4).G. Nasar, M. A. Khan, M. F. Warsi, M. Shahid, U. Khalil, and M. S. Khan, Macromol. Res., 24, 309 (2016).CrossRefGoogle Scholar(5).B. Huang, M. Cao, F. Nie, H. Huang, and C. Hu, Defence Technol., 9, 59 (2013).CrossRefGoogle Scholar(6).D. Krishnan, F. Kim, J. Luo, R. 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Coatings Technol., 261, 130 (2015).CrossRefGoogle ScholarCopyright information© The Polymer Society of Korea and Springer Sciene+Business Media Dordrecht 2016Authors and AffiliationsJae Hun Lee1Sang Jin Kim1Jung Soo Park2Jong Hak Kim1Email author1.Department of Chemical and Biomolecular EngineeringYonsei UniversitySeoulKorea2.The 4th R&D Institute 2nd DirectorateAgency for Defense and DevelopmentYuseong-gu, DaejeonKorea About this article CrossMark Print ISSN 1598-5032 Online ISSN 2092-7673 Publisher Name The Polymer Society of Korea About this journal Reprints and Permissions Article actions function trackAddToCart() { var buyBoxPixel = new webtrekkV3({ trackDomain: "springergmbh01.webtrekk.net", trackId: "196033507532344", domain: "link.springer.com", contentId: "springer_com.buybox", product: "10.1007/s13233-016-4117-2_Energetic Al/Fe2O3/PVDF composites", productStatus: "add", productCategory : { 1 : "ppv" }, customEcommerceParameter : { 9 : "link.springer.com" } }); buyBoxPixel.sendinfo(); } function trackSubscription() { var subscription = new webtrekkV3({ trackDomain: "springergmbh01.webtrekk.net", trackId: "196033507532344", domain: "link.springer.com", contentId: "springer_com.buybox" }); subscription.sendinfo({linkId: "inst. subscription info"}); } window.addEventListener("load", function(event) { var viewPage = new webtrekkV3({ trackDomain: "springergmbh01.webtrekk.net", trackId: "196033507532344", domain: "link.springer.com", contentId: "SL-article", product: "10.1007/s13233-016-4117-2_Energetic Al/Fe2O3/PVDF composites", productStatus: "view", productCategory : { 1 : "ppv" }, customEcommerceParameter : { 9 : "link.springer.com" } }); viewPage.sendinfo(); }); Log in to check your access to this article Buy (PDF)EUR 34,95 Unlimited access to full article Instant download (PDF) Price includes local sales tax if applicable Find out about institutional subscriptions Export citation .RIS Papers Reference Manager RefWorks Zotero .ENW EndNote .BIB BibTeX JabRef Mendeley Share article Email Facebook Twitter LinkedIn Cookies We use cookies to improve your experience with our site. 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