Self-assembly, structures and properties of three new Ni(II) coordination polymers derived from two different bis-pyridyl-bis-amide ligands and two aromatic polycarboxylates

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• 作者：HONGYAN LIN ; JUNJUN SUN ; GUOCHENG LIU∗ ; XIANG WANG…
• 关键词：Metal ; organic coordination polymer ; crystal structure ; bis ; pyridyl ; bis ; amide ligand ; fluorescence ; photocatalysis
• 刊名：Journal of Chemical Sciences
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：129
• 期：1
• 页码：9-20
• 全文大小：
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry/Food Science, general;
• 出版者：Springer India
• ISSN：0973-7103
• 卷排序：129

文摘

Three new Ni(II) coordination polymers exhibiting different 1D and 2D framework structures have been hydrothermally synthesized: [Ni(L 1)(1,3-BDC)(H ₂O) ₃] ⋅H₂O (1), [Ni(L 1)(1,3,5-HBTC)(H ₂O) ₃] (2), [Ni ₃(L 2)₃(1,3,5-BTC) ₂(H ₂O) ₈] ⋅12H ₂O (3) [L 1= N,N ′-bis(pyridin-3-yl)cyclohexane-1,4-dicarboxamide, L 2= N,N ′-bis(3-pyridyl)octandiamide, 1,3-H ₂BDC = 1,3-benzenedicarboxylic acid, 1,3,5-H ₃BTC = 1,3,5-benzenetricarboxylic acid]. X-ray single crystal diffraction analyses revealed that polymer 1 is a 2D interlaced layer based on the 1D [Ni(L 1)(1,3-BDC)(H ₂O) ₃] meso-helical chains. Polymer 2 is a 1D wave-shaped chain derived from the 1D [Ni(L 1)] _n chain and monodentate coordinated 1,3,5-HBTC anions. Polymer 3 possesses an interesting 2D layer containing the trinuclear [Ni ₃(1,3,5-BTC) ₂] substructural unit and 1D zigzag [Ni(L 2)] _n chain, representing a 3,4-connected {6 ⋅8 2} ₂ {62⋅82⋅10⋅12} topology. Finally, the adjacent 1D chains or the 2D layers are connected through hydrogen bonding interactions to construct 3D supramolecular networks. Further, the thermal stability, solid state fluorescent property and photocatalytic activity of 1–3 have been investigated.