Synthesis of naphthalene derivatives through inexpensive BF3·Et2O-catalyzed annulation reaction of arylacetaldehydes with arylalkynes

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• 作者：ShiKai Xiang (14843)
  Hao Hu (14843)
  Jing Ma (14843)
  YuanZhuo Li (14843)
  BiQin Wang (14843)
  Chun Feng (14843)
  KeQing Zhao (14843)
  Ping Hu (14843)
  XiaoZhen Chen (24843)
  
• 关键词：naphthalene derivatives ; BF3·Et2O ; arylacetaldehydes ; arylalkynes ; annulation reaction
• 刊名：SCIENCE CHINA Chemistry
• 出版年：2013
• 出版时间：July 2013
• 年：2013
• 卷：56
• 期：7
• 页码：945-951
• 全文大小：740KB
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• 作者单位：ShiKai Xiang (14843)
  Hao Hu (14843)
  Jing Ma (14843)
  YuanZhuo Li (14843)
  BiQin Wang (14843)
  Chun Feng (14843)
  KeQing Zhao (14843)
  Ping Hu (14843)
  XiaoZhen Chen (24843)
  
  14843. College of Chemistry and Materials Science, Sichuan Normal University, Chengdu, 610066, China
  24843. Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu, 610041, China
  

文摘

An inexpensive BF3·Et2O-catalyzed annulation reaction of arylacetaldehydes with arylalkynes has been developed. Various substituted phenylacetaldehydes and phenylacetylenes can undergo this reaction, producing corresponding α-aryl substituted naphthalene derivatives. Use of inexpensive and readily available BF3·Et2O catalyst constitutes the most attractive advantage of this transformation.