New possibilities of atomic emission spectrometry for the determination of elements with high excitation energies

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• 作者：E. N. Savinova ; Yu. S. Sukach ; G. M. Kolesov…
• 关键词：atomic emission spectrochemical analysis ; powder samples ; spectra of heavy excitable elements ; system of registration ; photoelectronic cells
• 刊名：Journal of Analytical Chemistry
• 出版年：2015
• 出版时间：May 2015
• 年：2015
• 卷：70
• 期：5
• 页码：578-585
• 全文大小：571 KB
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• 作者单位：E. N. Savinova (1)
  Yu. S. Sukach (1)
  G. M. Kolesov (1)
  D. A. Tyurin (1)
  
  1. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, ul. Kosygina 19, Moscow, 119991, Russia
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Analytical Chemistry
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1608-3199

文摘

Analytical characteristics of a high-temperature arc plasmatron with helium gas possessing high heat conductivity and high ionization potential as a plasma-forming gas have been investigated. A system of multichannel photoelectronic registration of spectra have been used in the scheme of a spectral instrument for atomic emission spectrochemical analysis. Based on the results obtained on examples of fluorine and chlorine, a procedure was proposed for the atomic emission spectrochemical determination of heavy excitable elements in powder samples.