Layer-by-layer self-assembly of bisdendrons: An unprecedented route to multilayer thin films

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• 作者：Ok-Joo Lee ; Valérie Maraval ; Anne-Marie Caminade ; Kyungwha Chung…
• 关键词：bisdendron ; layer ; by ; layer self ; assembly ; multilayer thin films ; surface plasmon resonance spectroscopy
• 刊名：Macromolecular Research
• 出版年：2016
• 出版时间：October 2016
• 年：2016
• 卷：24
• 期：10
• 页码：851-855
• 全文大小：1,009 KB
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Physical Chemistry
  Polymer Sciences
  Characterization and Evaluation of Materials
  Soft and Granular Matter, Complex Fluids and Microfluidics
  Nanochemistry
  Nanotec
  
• 出版者：The Polymer Society of Korea, co-published with Springer
• ISSN：2092-7673
• 卷排序：24

文摘

We present an unprecedented route to fabricate multilayer thin films by single component layer-by-layer molecular self-assembly. Tailored water-soluble phosphorus bisdendrons were obtained via core to core assembling of two dendrons bearing anionic groups at one end and quaternizable amino groups at the other end. Adsorption of a 1st bisdendron monolayer on a charged substrate followed by sequential quaternization/deposition of a 2nd layer leads to a stepwise growth of multilayers. By this way, homogeneous multilayer thin films were successfully constructed as confirmed by spectroscopic and microscopic analysis.Keywordsbisdendronlayer-by-layer self-assemblymultilayer thin filmssurface plasmon resonance spectroscopyReferences(1).S. Ameen, M. Song, D.-G. Kim, Y.-B. Im, H.-K. Seo, Y. S. Kim, and H.-S. Shin, Macromol. Res., 20, 30 (2012).CrossRefGoogle Scholar(2).K. R. Yoon, H. Lee, B. K. Rhee, and C. Jung, Macromol. Res., 12, 581 (2004).CrossRefGoogle Scholar(3).G. 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Gopalan, Polymers, 7, 1346 (2015).CrossRefGoogle ScholarCopyright information© The Polymer Society of Korea and Springer Sciene+Business Media Dordrecht 2016Authors and AffiliationsOk-Joo Lee17Valérie Maraval2Anne-Marie Caminade2Kyungwha Chung3King Hang Aaron Lau4Kwanwoo Shin5Jean-Pierre Majoral2Email authorWolfgang Knoll6Email authorDong Ha Kim3Email author1.Max Planck Institute for Polymer ResearchMainzGermany2.Laboratoire de Chimie de Coordination, CNRSToulouse CedexFrance3.Department of Chemistry and Nano Science, Division of Molecular and Life Sciences, College of Natural SciencesEwha Womans UniversitySeoulKorea4.Department of Pure and Applied ChemistryUniversity of StrathclydeGlasgowUK5.Department of Chemistry, Interdisciplinary Program of Integrated BiotechnologySogang UniversitySeoulKorea6.AIT Austrian Institute of TechnologyViennaAustria7.Korean Intellectual Property Office, Gov. 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