Effect of Fe Substitution on Thermoelectric Properties of Fe x In4?em class="a-plus-plus">x Se3 Compounds

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• 作者：Gen Li (1)
  Junyou Yang (1)
  Ye Xiao (1)
  Liangwei Fu (1)
  Jiangying Peng (1)
  Yuan Deng (2)
  Pinwen Zhu (3)
  Haixue Yan (4)
  
• 关键词：In4Se3 ; MA ; HP ; Fe substitution ; thermoelectric properties
• 刊名：Journal of Electronic Materials
• 出版年：2013
• 出版时间：April 2013
• 年：2013
• 卷：42
• 期：4
• 页码：675-678
• 全文大小：451KB
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• 作者单位：Gen Li (1)
  Junyou Yang (1)
  Ye Xiao (1)
  Liangwei Fu (1)
  Jiangying Peng (1)
  Yuan Deng (2)
  Pinwen Zhu (3)
  Haixue Yan (4)
  
  1. State Key Laboratory of Material Processing and Die & Mould Technology, Huazhong University of Science and Technology, Wuhan, 430074, China
  2. Beihang University, Beijing, 100191, China
  3. National Lab of Superhard Materials, Jilin University, Changchun, 130012, People’s Republic of China
  4. School of Engineering and Materials Science, Queen Mary University of London, London, E1 4NS, UK
  
• ISSN：1543-186X

文摘

Starting from elemental powder mixtures of Fe x In4?em class="a-plus-plus">x Se3 (x?=?0, 0.05, 0.1, 0.15), polycrystalline In4Se3-based compounds with homogeneous microstructures were prepared by mechanical alloying (MA) and hot pressing (HP). With the increase of x from 0 to 0.15, the electrical resistivity and the absolute value of the Seebeck coefficient increased, while the thermal conductivity first decreased and then increased. The maximal dimensionless figure of merit ZT of 0.44 was obtained for the Fe x In4?em class="a-plus-plus">x Se3 (x?=?0.05) sample at 723?K.