Synthesis of high-voltage spinel LiNi0.5Mn1.5O4 material for lithium-ion batteries by a metal-cholate supramolecular hydrogel as precursor

详细信息    查看全文

• 作者：Guozheng Ma ; Yu Zhang ; Jintai Lin ; Zhanjun Chen…
• 关键词：LiNi0.5Mn0.5O4 ; Supramolecular hydrogel ; Electrode materials ; Spinel
• 刊名：Journal of Solid State Electrochemistry
• 出版年：2015
• 出版时间：November 2015
• 年：2015
• 卷：19
• 期：11
• 页码：3365-3372
• 全文大小：1,810 KB
• 参考文献：1.Ma X, Kang B, Ceder G (2010) J Electrochem Soc 157:925–931CrossRef
  2.Zhong Q, Bonakdarpour A, Zhang M, Gao Y, Dahn JR (1997) J Electrochem Soc 144:205–213CrossRef
  3.Amarilla JM, Rojas RM, Rojo JM (2011) J Power Sources 196:5951–5959CrossRef
  4.Liu GQ, Wen L, Liu YM (2010) J Solid State Electrochem 14:2191–2202CrossRef
  5.Arico AS, Bruce P, Scrosati B, Tarascon JM, Schalkwijk WV (2005) Nat Mater 4:366–377CrossRef
  6.Wang H, Tan TA, Yang P, Lai MO, Lu L (2011) J Phys Chem C 115:6102–6110CrossRef
  7.Kunduraci M, Al-Sharab JF, Amatucci GG (2006) Chem Mater 18:3585–3592CrossRef
  8.Amdouni N, Zaghib K, Gendron F, Mauger A, Julien CM (2006) Ionics 12:117–126CrossRef
  9.Yang T, Zhang N, Lang Y, Sun K (2011) Electrochim Acta 56:4058–4064CrossRef
  10.Fan YK, Wang JM, Ye XB, Zhang JQ (2007) Mater Chem Phys 103:19–23CrossRef
  11.Zhao QL, Ye NQ, Li L, Yan F (2010) Rare Metal Mater Eng 39(10):1715–1718CrossRef
  12.Huang XK, Zhang QS (2011) J Electrochem Soc 158(2):A139–A145CrossRef
  13.Kim JH, Myung ST, Sun YK (2004) Electrochim Acta 49:219–227CrossRef
  14.Xu HY, Xie S, Ding N (2006) Electrochim Acta 51(21):4352–4357CrossRef
  15.Zhang L, Lv XY, Wen YX (2009) J Alloys Compd 480(2):802–805CrossRef
  16.Yu LH, Cao YL, Yang HX, Ai XP (2006) J Solid State Electrochem 10:283–287CrossRef
  17.Elliott JE, Macdonald M, Nie J, Bowman CN (2004) Polymer 45:1503–1510CrossRef
  18.Ozay O, Ekici S, Baran Y, Aktas N, Sahiner N (2009) Water Res 43:4403–4411CrossRef
  19.Qiao Y, Lin YY, Wang YJ, Yang ZY, Liu J, Zhou J, Yan Y, Huang JB (2009) Nano Lett 9:4500–4504CrossRef
  20.Chakrabarty A, Maitra U, Das AD (2012) J Mater Chem 22:18268–18274CrossRef
  21.Cai LC, Wang YJ, Li J, Huang JB (2012) Acta Phys-Chim Sin 28:2298–2304
  22.Bhowmik S, Banerjee S, Maitra U (2010) Chem Commun 45:8642–8644CrossRef
  23.Qiao Y, Wang YJ, Yang ZY, Lin YY, Huang JB (2011) Chem Mater 23:1182–118725CrossRef
  24.Qiao Y, Chen HF, Lin YY, Yang ZY, Cheng XH, Huang JB (2011) J Phys Chem C 115:7323–7330CrossRef
  25.Chen ZJ, Zhao RR, Du P, Hu H, Wang T, Zhu LC, Chen HY (2014) J Mater Chem A 2:12835–12848CrossRef
  26.Santhanam R, Rambabu B (2010) J Power Sources 195:5442–5451CrossRef
  27.Hwang BJ, Wu YW, Venkateswarlu M, Cheng MY, Santhanam R (2009) J Power Sources 193:828–833CrossRef
  28.Reddy MV, Cheng HY, Tham JH, Yuan CY, Goh HL, Chowdari BVR (2012) Electrochim Acta 62:269–275CrossRef
  29.Arrebol JC, Caballero A, Cruz M, Hernan L, Morales J, Castellon ER (2006) Adv Funct Mater 16:1904–1912CrossRef
  30.Fang HS, Li LP, Li GS (2007) J Power Sources 167:223–227CrossRef
  31.Liu J, Manthiram A (2009) J Electrochem Soc 156(1):A66–A72CrossRef
  32.Kunduraci M, Al-sharab JF, Amatucci GG (2006) Chem Mater 18(15):3585–3592CrossRef
  33.Chemelewski KR, Lee ES, Li W, Manthiram A (2013) Chem Mater 25:2890–2897CrossRef
  34.Qiao Y, Lin YY, Yang ZY, Chen HF, Zhang SF, Yan Y, Huang JB (2010) J Phys Chem B 114:11725–11730CrossRef
  35.Zhang XL, Cheng FY, Zhang K, Liang YL, Yang SQ, Liang J, Chen J (2012) RSC Adv 2:5669–5675CrossRef
  36.Markovsky B, Talyossef Y, Salitra G (2004) Electrochem Commun 6(8):821–826CrossRef
  37.Fang X, Lu Y, Ding N, Feng XY, Liu C, Chen CH (2010) Electrochim Acta 55:832–837CrossRef
  38.Lee HW, Muralidharan P, Mari CM, Ruffo R, Kim DK (2011) J Power Sources 196:10712–1071639CrossRef
  39.Feng JJ, Huang ZP, Guo C, Chernova NA, Upreti S, Whittingham MS (2013) ACS Appl Mater Interfaces 5:10227–10232CrossRef
  40.Zhang GB, Wang YY, Yu YQ, Chen CH (2012) J Power Sources 205:385–393CrossRef
  41.Xiao LF, Zhao YQ, Yang YY, Ai XP, Yang HX, Cao YL (2008) J Solid State Electrochem 12:687–691CrossRef
  42.Mao J, Dai K, Zhai Y (2012) Electrochim Acta 63:381–390CrossRef
  
• 作者单位：Guozheng Ma (1)
  Yu Zhang (1)
  Jintai Lin (1)
  Zhanjun Chen (1)
  Ruirui Zhao (1)
  Pengyang Tong (1)
  Liya Zou (1)
  Hongyu Chen (1)
  
  1. School of Chemistry and Environment, South China Normal University, Guangzhou, 510006, People’s Republic of China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Physical Chemistry
  Analytical Chemistry
  Industrial Chemistry and Chemical Engineering
  Characterization and Evaluation Materials
  Condensed Matter
  Electronic and Computer Engineering
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1433-0768

文摘

High-voltage cathode material LiNi_0.5Mn_1.5O₄ has been first synthesized by a novel metal-cholated supramolecular hydrogel as precursor. The structural analysis was investigated by X-ray powder diffraction, scanning electronic microscope, and Fourier transform infrared spectroscopy. The results indicated that the as-products possessed well constructed spinel structure and high crystallinity and pure phase through adding optimal amount of cholic acid. The electrochemical properties were also investigated, and its results showed that the LiNi_0.5Mn_1.5O₄ material exhibited enhanced rate capacity and cycling properties as electrode materials in lithium cells mainly due to the improved crystallinity and higher pure phase. In a word, this new approach provides an alternative and promising route for the fabrication of cathode materials with perfect octahedron structure and excellent electrochemical properties using metal-driven hydrogels as template.