The Effect of Thermal Pre-Treatment on Structure, Composition, Basicity and Catalytic Activity of Mg/Al Mixed Oxides
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- 作者：Libor ?apek (1)
Petr Kutálek (1)
Lucie Smoláková (1)
Martin Hájek (1)
Ivana Troppová (1)
David Kubi?ka (2) - 关键词：Mg/Al mixed oxides ; Structure analysis ; Basic sites ; Thermal pre ; treatment ; Transesterification
- 刊名：Topics in Catalysis
- 出版年：2013
- 出版时间：June 2013
- 年：2013
- 卷：56
- 期：9-10
- 页码：586-593
- 全文大小：637KB
- 参考文献：1. Corma A, Iborra S, Miquel S, Primo J (1998) J Catal 173:315 CrossRef
2. Liu Y, Lotero E, Goodwin JG, Mo X (2007) Appl Catal 331:138 CrossRef
3. Abello S, Medina F, Tichit D, Perez-Ramirez J, Sueiras JE, Salagre P, Cesteros Y (2007) Appl Catal B 70:577 CrossRef
4. Rao KK, Gravelle M, Valente JS, Figueras F (1998) J Catal 173:115 CrossRef
5. Climent MJ, Corma A, Iborra S, Primo J (1995) J Catal 151:60 CrossRef
6. Corma A, Fornes V, Martinaranda RM, Rey F (1992) J Catal 134:58 CrossRef
7. Prescott HA, Li ZJ, Kemnitz E, Trunschke A, Deutsch J, Lieske H, Auroux A (2005) J Catal 234:119 CrossRef
8. Velu S, Swamy CS (1994) Appl Catal 119:241 CrossRef
9. Garcia-Sancho C, Moreno-Tost R, Merida-Robles JM, Santamaria-Gonzalez J, Jimenez-Lopez A, Torres PM (2011) Catal Today 167:84 CrossRef
10. Kustrowski P, Chmielarz L, Bozek E, Sawalha M, Roessner F (2004) Mater Res Bull 39:263 CrossRef
11. Alvarez MG, Chimentao RJ, Figueras F, Medina F (2012) Appl Clay Sci 58:16 CrossRef
12. Diez VK, Apesteguia CR, Di Cosimo JI (2003) J Catal 215:220 CrossRef
13. Silva CCCM, Ribeiro NFP, Souza MMVM, Aranda DAG (2010) Fuel Process Technol 91:205 CrossRef
14. Veloso CO, Perez CN, de Souza BM, Lima EC, Dias AG, Monteiro JLF, Henriques CA (2008) Microporous Mesoporous Mater 107:23 CrossRef
15. Di Cosimo JI, Diez VK, Xu M, Iglesia E, Apesteguia CR (1998) J Catal 178:499 CrossRef
16. Prinetto F, Ghiotti G, Durand R, Tichit D (2000) J Phys Chem B 104:11117 CrossRef
17. Shen JY, Tu M, Hu C (1998) J Solid State Chem 137:295 CrossRef
18. Xie WL, Peng H, Chen LG (2006) J Mol Catal a-Chem 246:24 CrossRef
19. Kim MJ, Park SM, Chang DR, Seo G (2010) Fuel Process Technol 91:618 CrossRef
20. Alvarez MG, Segarra AM, Contreras S, Sueiras JE, Medina F, Figueras F (2010) Chem Eng J 161:340 CrossRef
21. Di Cosimo JI, Apesteguia CR, Gines MJL, Iglesia E (2000) J Catal 190:261 CrossRef
22. Sree R, Babu NS, Prasad PSS, Lingaiah N (2009) Fuel Process Technol 90:152 CrossRef
23. Ma FR, Hanna MA (1999) Bioresource Technol 70:1 CrossRef
24. Kubi?ková I, Kubi?ka D (2010) Waste Biomass Valoris 1:293 CrossRef
25. Benjapornkulaphong S, Ngamcharussrivichai C, Bunyakiat K (2009) Chem Eng J 145:468 CrossRef
26. Gryglewicz S (1999) Bioresource Technol 70:249 CrossRef
27. Yang ZQ, Xie WL (2007) Fuel Process Technol 88:631 CrossRef
28. Queiroz RM, Pires LHO, de Souza RCP, Zamian JR, de Souza AG, da Rocha GN, da Costa CEF (2009) J Therm Anal Calorim 97:163 CrossRef
29. Lopez DE, Goodwin JG, Bruce DA, Lotero E (2005) Appl Catal 295:97 CrossRef
30. Xie WL, Li HT (2006) J Mol Catal 255:1 CrossRef
31. Zeng HY, Feng Z, Deng X, Li YQ (2008) Fuel 87:3071 CrossRef
32. Di Serio M, Ledda M, Cozzolino M, Minutillo G, Tesser R, Santacesaria E (2006) Ind Eng Chem Res 45:3009 CrossRef
33. Parida K, Das J (2000) J Mol Catal 151:185 CrossRef
34. Tittabutt T, Trakarnpruk W (2008) Ind Eng Chem Res 47:2176 CrossRef
35. Antunes WM, Veloso CD, Henriques CA (2008) Catal Today 133:548 CrossRef
36. Winter F, van Dillen AJ, de Jong KP (2005) Chem Commun. doi:10.1039/B506173Cv
37. Jenkins R, Snyder RL (1996) John Wiley & Sons Inc., New York
38. Cavani F, Trifiro F, Vaccari A (1991) Catal Today 11:173 CrossRef
39. Mackenzie KJD, Meinhold RH, Sherriff BL, Xu Z (1993) J Mater Chem 3:1263 CrossRef
40. Constantino VRL, Pinnavaia TJ (1995) Inorg Chem 34:883 CrossRef
41. Reichle WT, Kang SY, Everhardt DS (1986) J Catal 101:352 CrossRef
42. Bolognini M, Cavani F, Scagliarini D, Flego C, Perego C, Saba M (2002) Catal Today 75:103 CrossRef
43. Grabowska H, Zawadzki M, Syper L, Mista W (2005) Appl Catal 292:208 CrossRef
44. Zeng HY, Deng X, Wang YJ, Liao KB (2009) AIChE J 55:1229 CrossRef
45. Brito A, Borges ME, Garin M, Hernandez A (2009) Energy Fuel 23:2952 CrossRef
46. Gomes JFP, Puna JFB, Goncalves LM, Bordado JCM (2011) Energy 36:6770 CrossRef
47. Deng X, Fang Z, Liu YH, Yu CL (2011) Energy 36:777 CrossRef
48. Navajas A, Campo I, Arzamendi G, Hernandez WY, Bobadilla LF, Centeno MA, Odriozola JA, Gandia LM (2010) Appl Catal B 100:299 CrossRef
49. Shumaker JL, Crofcheck C, Tackett SA, Santillan-Jimenez E, Morgan T, Ji Y, Crocker M, Toops TJ (2008) Appl Catal B 82:120 CrossRef - 作者单位：Libor ?apek (1)
Petr Kutálek (1)
Lucie Smoláková (1)
Martin Hájek (1)
Ivana Troppová (1)
David Kubi?ka (2)
1. Department of Physical Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, 532 10, Pardubice, Czech Republic
2. Research Institute of Inorganic Chemistry, RENTECH-UniCRE, Chempark Litvínov, Zálu?í, 436 70, Litvínov, Czech Republic - ISSN：1572-9028
文摘
The goal of this work is to study the effect of thermal pre-treatment of Mg/Al mixed oxides (450-,050?°C) on their structure, basicity and catalytic activity in transesterification of rapeseed oil. The catalytic activity of Mg/Al catalysts was shown to depend not only on the amount of basic sites, but also on crystallite size of MgO, specific surface area and population of medium/strong basic sites. Moreover, high stability of Mg/Al-550 was established by re-using the catalyst four times. It was associated with negligible magnesium leaching from the solid catalyst to liquid phases.