Effective reinforcement of epoxy composites with hyperbranched liquid crystals grafted on microcrystalline cellulose fibers

详细信息    查看全文

• 作者：Qiyun Luo ; Yuqi Li ; Lulu Pan ; Laifu Song ; Jin yang…
• 刊名：Journal of Materials Science
• 出版年：2016
• 出版时间：October 2016
• 年：2016
• 卷：51
• 期：19
• 页码：8888-8899
• 全文大小：2,388 KB
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Materials Science
  Characterization and Evaluation Materials
  Polymer Sciences
  Continuum Mechanics and Mechanics of Materials
  Crystallography
  Mechanics
  
• 出版者：Springer Netherlands
• ISSN：1573-4803
• 卷排序：51

文摘

Interface design plays a crucial role in developing superior mechanical performance of nature fibers/polymer composites (NPC). Herein, microcrystalline cellulose fibers (MCFs), extracted from sisal fibers, were modified by function end-group hyperbranched liquid crystals (HLP) with respect to improve the wettability and interactions between the MCFs and epoxy resin (EP). The HLP that modified MCFs (HLP-MCFs) were studied by Fourier transform infrared spectroscopy, scanning electron microscopy, X-ray photoelectron spectroscopy, X-ray diffraction, and polarizing microscope. The results showed that the MCFs can be successfully modified by the HLP, which would provide strong MCFs/matrix interfacial adhesion. Therefore, the addition of HLP-MCFs was found to produce significant enhancements in the mechanical and thermal properties of EP. In particular, at 1.0 wt% filler loading, the flexural strength, tensile strength, impact strength, and flexural modulus of the HLP-MCFs/EP composites increased by 60, 69, 130, and 192 %, respectively, as well as the glass transition temperature increased by a notable 42.9 °C. It is anticipated that our current work would inform ongoing efforts to exploit more efficient method to overcome the poor nature fiber/polymer adhesion in the interface region and broad implications for the development of the NPC for engineering applications.Electronic supplementary materialThe online version of this article (doi:10.1007/s10853-016-0136-9) contains supplementary material, which is available to authorized users.