Electromagnetic response of magnetic graphene hybrid fillers and their evolutionary behaviors

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• 作者：Lin Liu ; Xing-Ming Bian ; Zhi-Ling Hou…
• 刊名：Journal of Materials Science: Materials in Electronics
• 出版年：2016
• 出版时间：March 2016
• 年：2016
• 卷：27
• 期：3
• 页码：2760-2772
• 全文大小：2,618 KB
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• 作者单位：Lin Liu (1)
  Xing-Ming Bian (1)
  Zhi-Ling Hou (2)
  Chan-Yuan Wang (3)
  Zhi Sheng Li (1)
  Hui Dong Hu (1)
  Xin Qi (1)
  Xu Zhang (1)
  
  1. State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources, North China Electric Power University, Beijing, 102206, People’s Republic of China
  2. School of Science, Beijing University of Chemical Technology, Beijing, 100029, People’s Republic of China
  3. 310 Department, Third Institution of China Aerospace Science and Industry, Beijing, 100071, People’s Republic of China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Optical and Electronic Materials
  Characterization and Evaluation Materials
  
• 出版者：Springer New York
• ISSN：1573-482X

文摘

To understand the principles and mechanisms of the graphene-based electromagnetic response composites, we prepare magnetic graphene–Fe₃O₄ (G–F) hybrid materials and study the electromagnetic properties in the frequency region of 2–18 GHz. The introduction of Fe₃O₄ nanoparticles is found to play a dominant role in the complex permittivity, resulting in changing the surface polarization and interfacial resistivity of the graphene-based fillers. These influences have been found to greatly impact the corresponding microwave absorption and electromagnetic shielding performance. Owing to the syngeneic effects of G and Fe₃O₄, the wax-based composites with G–F presented effective microwave absorption (<−10 dB) and sufficient electromagnetic shielding performance (>20 dB) in the investigated region. The associated mechanisms based on tuning the electromagnetic response of the graphene-based composites via the unique Fe₃O₄ interfaces have been intensively discussed, which promises great guidance in rationally designing and fabricating advanced graphene-based electromagnetic response materials.