Synthesis and Evaluation of Microstructural and Magnetic Properties of Cr3+ Substitution Barium Hexaferrite Nanoparticles (BaFe10.5−x Al1.5Cr x O _{详细信息    查看全文}

• 作者：Akbar Hojjati Najafabadi ; Ali Ghasemi ; Reza Mozaffarinia
• 刊名：Journal of Cluster Science
• 出版年：2016
• 出版时间：May 2016
• 年：2016
• 卷：27
• 期：3
• 页码：965-978
• 全文大小：2,051 KB
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Inorganic Chemistry
  Physical Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1572-8862
• 卷排序：27

文摘

Pure barium ferrite and BaFe_10.5−xAl_1.5Cr_xO₁₉ (x = 0, 0.5, 1.0, 1.5, 2.0) nanoparticles were synthesized by auto-combustion sol–gel method. The effect of substituting Fe3+ ions by Al3+ and Cr3+ ions on the structural, chemical composition, morphology and magnetic properties of BaFe₁₂O₁₉ and BaFe_10.5−xAl_1.5Cr_xO₁₉ hexaferrites have been investigated using X-ray diffraction, Fourier transform infrared spectroscopy, field emission scanning electron microscopy and vibrating sample magnetometer (VSM), respectively. The results confirmed that the hexagonal phase has been formed in all of nanoparticles and the value of lattice parameter (c) decreased, while the value of lattice parameter (a) remained nearly constant with the increase in Cr3+ ions contents in comparison to pure barium ferrite. The crystallite size and mean particle size of the nanoparticles lie in the ranges 33–42 and 35–70 nm, respectively. The VSM measurements show that with substituting Al and Cr cations in the hexagonal structure of barium ferrite, the saturation magnetization (M_s) and remanence magnetization (M_r) of the nanoparticles reduce, while coercive field (H_c) increased from 4.45 kOe for pure barium ferrite to 6.9 kOe for BaFe_10.5Al_1.5O₁₉ (x = 0) due to the increase in the magnetocrystalline anisotropy and the decrease of the particle size.KeywordsHexaferriteCr-substitutedStructural characterizationMagnetic properties