Single-particle speciation of alkylamines in ambient aerosol at five European sites

详细信息    查看全文

• 作者：Robert M. Healy ; Greg J. Evans ; Michael Murphy…
• 关键词：Aerosols ; Particulates ; Agriculture ; Speciation ; Organic compounds ; Trace organic compounds
• 刊名：Analytical and Bioanalytical Chemistry
• 出版年：2015
• 出版时间：August 2015
• 年：2015
• 卷：407
• 期：20
• 页码：5899-5909
• 全文大小：1,146 KB
• 参考文献：1.Ge X, Wexler AS, Clegg SL (2011) Atmospheric amines—part I. A review. Atmos Environ 45(3):524-46. doi:10.-016/?j.?atmosenv.-010.-0.-12 View Article
  2.Murphy SM, Sorooshian A, Kroll JH, Ng NL, Chhabra P, Tong C, Surratt JD, Knipping E, Flagan RC, Seinfeld JH (2007) Secondary aerosol formation from atmospheric reactions of aliphatic amines. Atmos Chem Phys 7(9):2313-337View Article
  3.Silva PJ, Erupe ME, Price D, Elias J, Malloy QG, Li Q, Warren B, Cocker DR (2008) Trimethylamine as precursor to secondary organic aerosol formation via nitrate radical reaction in the atmosphere. Environ Sci Technol 42(13):4689-696. doi:10.-021/?es703016v View Article
  4.Sellegri K, Hanke M, Umann B, Arnold F, Kulmala M (2005) Measurements of organic gases during aerosol formation events in the boreal forest atmosphere during QUEST. Atmos Chem Phys 5(2):373-84. doi:10.-194/?acp-5-373-2005 View Article
  5.Pratt KA, Hatch LE, Prather KA (2009) Seasonal volatility dependence of ambient particle phase amines. Environ Sci Technol 43(14):5276-281. doi:10.-021/?es803189n View Article
  6.Ge X, Wexler AS, Clegg SL (2011) Atmospheric amines—part II. Thermodynamic properties and gas/particle partitioning. Atmos Environ 45(3):561-77View Article
  7.Schade G, Crutzen P (1995) Emission of aliphatic amines from animal husbandry and their reactions: potential source of N2O and HCN. J Atmos Chem 22(3):319-46. doi:10.-007/?BF00696641 View Article
  8.Dentener F, Crutzen P (1994) A three-dimensional model of the global ammonia cycle. J Atmos Chem 19(4):331-69. doi:10.-007/?BF00694492 View Article
  9.Bzdek BR, Ridge DP, Johnston MV (2011) Amine reactivity with charged sulfuric acid clusters. Atmos Chem Phys 11(16):8735-743. doi:10.-194/?acp-11-8735-2011 View Article
  10.Bzdek BR, Ridge DP, Johnston MV (2010) Amine exchange into ammonium bisulfate and ammonium nitrate nuclei. Atmos Chem Phys 10(8):3495-503. doi:10.-194/?acp-10-3495-2010 View Article
  11.Erupe ME, Viggiano AA, Lee SH (2011) The effect of trimethylamine on atmospheric nucleation involving H2SO4. Atmos Chem Phys 11(10):4767-775. doi:10.-194/?acp-11-4767-2011 View Article
  12.Smith JN, Barsanti KC, Friedli HR, Ehn M, Kulmala M, Collins DR, Scheckman JH, Williams BJ, McMurry PH (2010) Observations of aminium salts in atmospheric nanoparticles and possible climatic implications. Proc Natl Acad Sci 107(15):6634-639. doi:10.-073/?pnas.-912127107 View Article
  13.Sullivan AP, Weber RJ (2006) Chemical characterization of the ambient organic aerosol soluble in water: 2. Isolation of acid, neutral, and basic fractions by modified size-exclusion chromatography. J Geophys Res Atmos 111(D5):D05315. doi:10.-029/-005JD006486
  14.Gorzelska K, Talbot RW, Klemm K, Lefer B, Klemm O, Gregory GL, Anderson B, Barrie LA (1994) Chemical composition of the atmospheric aerosol in the troposphere over the Hudson Bay lowlands and Quebec-Labrador regions of Canada. J Geophys Res Atmos 99(D1):1763-779. doi:10.-029/-3JD02090 View Article
  15.Yang H, Yu JZ, Ho SSH, Xu J, Wu W-S, Wan CH, Wang X, Wang X, Wang L (2005) The chemical composition of inorganic and carbonaceous materials in PM2.5 in Nanjing, China. Atmos Environ 39(20):3735-749. doi:10.-016/?j.?atmosenv.-005.-3.-10 View Article
  16.Huang RJ, Li WB, Wang YR, Wang QY, Ho KF, Cao JJ, Wang GH, Chen X, Haddad IE, Zhuang ZX, Wang XR, Prév?t ASH, O’Dowd CD, Hoffmann T (2014) Determination of alkyl amines in atmospheric aerosol particles: a comparison of gas chromatography–mass spectrometry and ion chromatography approaches. Atmos Meas Tech Discuss 7(3):2127-152. doi:10.-194/?amtd-7-2127-2014 View Article
  17.Namie?nik J, Jastrz?bska A, Zygmunt B (2003) Determination of volatile aliphatic amines in air by solid-phase microextraction coupled with gas chromatography with flame ionization detection. J Chromatogr A 1016(1):1-. doi:10.-016/?S0021-9673(03)01296-2 View Article
  18.Chang I-H, Lee C-G, Lee DS (2003) Development of an automated method for simultaneous determination of low molecular weight aliphatic amines and ammonia in ambient air by diffusion scrubber coupled to ion chromatography. Anal Chem 75(22):6141-146. doi:10.-021/?ac0347314 View Article
  19.Facchini MC, Decesari S, Rinaldi M, Carbone C, Finessi E, Mircea M, Fuzzi S, Moretti F, Tagliavini E, Ceburnis D, O’Dowd CD (2008) Important source of marine secondary organic aerosol from biogenic amines. Environ Sci Technol 42(24):9116-121. doi:10.-021/?es8018385 View Article
  20.VandenBoer TC, Petroff A, Markovic MZ, Murphy JG (2011) Size distribution of alkyl amines in continental particulate matter and their online detection in the gas and particle phase. Atmos Chem Phys 11(9):4319-332. doi:10.-194/?acp-11-4319-2011 View Article
  21.Aiken AC, Salcedo D, Cubison MJ, Huffman JA, DeCarlo PF, Ulbrich IM, Docherty KS, Sueper D, Kimmel JR, Worsnop DR, Trimborn A, Northway M, Stone EA, Schauer JJ, Volkamer RM
• 作者单位：Robert M. Healy (1) (2)
  Greg J. Evans (1)
  Michael Murphy (1)
  Berko Sierau (3)
  Jovanna Arndt (2)
  Eoin McGillicuddy (2)
  Ian P. O’Connor (2)
  John R. Sodeau (2)
  John C. Wenger (2)
  
  1. Southern Ontario Centre for Atmospheric Aerosol Research, University of Toronto, 200 College Street, Toronto, M5S 3E5, Ontario, Canada
  2. Department of Chemistry and Environmental Research Institute, University College Cork, Lee Road, Cork, Ireland
  3. Institute for Atmospheric and Climate Science, ETH Zurich, 8092, Zurich, Switzerland
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Analytical Chemistry
  Food Science
  Inorganic Chemistry
  Physical Chemistry
  Monitoring, Environmental Analysis and Environmental Ecotoxicology
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1618-2650

文摘

Alkylamines are associated with both natural and anthropogenic sources and have been detected in ambient aerosol in a variety of environments. However, little is known about the ubiquity or relative abundance of these species in Europe. In this work, ambient single-particle mass spectra collected at five sampling sites across Europe have been analysed for their alkylamine content. The aerosol time-of-flight mass spectrometer (ATOFMS) data used were collected in Ireland (Cork), France (Paris, Dunkirk and Corsica) and Switzerland (Zurich) between 2008 and 2013. Each dataset was queried for mass spectral marker ions associated with the following ambient alkylamines: dimethylamine (DMA), trimethylamine (TMA), diethylamine (DEA), triethylamine (TEA), dipropylamine (DPA) and tripropylamine (TPA). The fraction of ambient particles that contained detectable alkylamines ranged from 1 to 17?% depending on location, with the highest fractions observed in Paris and Zurich in the winter months. The lowest fractions were observed at coastal sites, where the influence of animal husbandry-related alkylamine emissions is also expected to be lowest. TMA was the most ubiquitous particle phase alkylamine detected and was observed at all locations. Alkylamines were found to be internally mixed with both sulphate and nitrate for each dataset, suggesting that aminium salt formation may be important at all sites investigated. Interestingly, in Corsica, all alkylamine particles detected were also found to be internally mixed with methanesulphonic acid (MSA), indicating that aminium methanesulphonate salts may represent a component of marine ambient aerosol in the summer months. Internal mixing of alkylamines with sea salt was not observed, however. Alkylamine-containing particle composition was found to be reasonably homogeneous at each location, with the exception of the Corsica and Dunkirk sites, where two and four distinct mixing states were observed, respectively.