Formation of 1D-Chain via C–H?Cl Interaction Utilizing [(L3)ZnIICl2] (L3?=?2-[3-(2-Pyridyl)pyrazol-1-ylmethyl]-(1-methylim

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• 作者：Vibha Mishra (1)
  Anuj Kumar Sharma (1)
  Rabindranath Mukherjee (1) (2)
  
• 关键词：ZnIICl2 ; containing coordination compound ; Neutral tridentate N ; donor nonplanar ligand ; Crystal structure ; Noncovalent (C–H?Cl) interactions ; 1D chain
• 刊名：Proceedings of the National Academy of Sciences, India Section A: Physical Sciences
• 出版年：2014
• 出版时间：June 2014
• 年：2014
• 卷：84
• 期：2
• 页码：315-320
• 全文大小：518 KB
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• 作者单位：Vibha Mishra (1)
  Anuj Kumar Sharma (1)
  Rabindranath Mukherjee (1) (2)
  
  1. Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, 208 016, India
  2. Indian Institute of Science Education and Research Kolkata, Mohanpur Campus, Mohanpur, 741 252, India
  
• ISSN：2250-1762

文摘

Reaction of 2-[3-(2-pyridyl)pyrazol-1-ylmethyl](1-methylimidazole) (L3) with ZnCl2 affords [(L3)ZnIICl2] 1. Crystal structure analysis of 1 reveals that the ZnII ion assumes a slightly distorted square-pyramidal geometry with coordination by the tridentate nonplanar ligand L3, providing a pyridine, a pyrazole and an imidazole N donors and two chloride ions. Notably, secondary interactions [C–H?Cl (–CH2-hydrogen of the spacer and –CH3 hydrogen of 1-methylimidazole)] triggered by ZnII-coordinated chloride ions acting as hydrogen-bonding acceptors generates self-complementary dimeric tectons, which lead to 1D supramolecular chain.