Nickel(II) 伪-diimine catalysts with carboxyl groups for ethylene oligomerization and polymerization

详细信息    查看全文

• 作者：Bing Liu ; Meng-zhe Fang ; Su-yun Jie 浠嬬礌浜?/a> ; Zhi-yang Bu…
• 关键词：伪 ; Diimine ; Nickel ; Ethylene ; Oligomerization ; Polymerization
• 刊名：Chinese Journal of Polymer Science
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：34
• 期：2
• 页码：221-228
• 全文大小：774 KB
• 参考文献：1.Rapp茅, A.K., Skiff, W.M. and Casewit, C.J., Chem. Rev., 2000, 100(4): 1435CrossRef
  2.Ittel, S.D., Johnson, L.K. and Brookhart, M., Chem. Rev., 2000, 100(4): 1169CrossRef
  3.Gibson, V.C and Spitzmesser, S.K., Chem. Rev., 2003, 103(1): 283CrossRef
  4.Wang, S.L., Sun, W.H. and Redshaw, C., J. Organomet. Chem., 2014, 751: 717CrossRef
  5.Johnson, L.K., Killian, C.M. and Brookhart, M., J. Am. Chem. Soc., 1995, 117(23): 6414CrossRef
  6.Liu, Q.Y., Zhang, W.J., Jia, D.D., Hao, X., Redshaw, C. and Sun, W.H., Appl. Catal. A: Gen., 2014, 475: 195CrossRef
  7.Jia, D.D., Zhang, W.J., Liu, W.L., Wang, L., Redshaw, C. and Sun, W.H., Catal. Sci. Technol., 2013, 3(10): 2737CrossRef
  8.Natta, G., Pino, P., Corradini, P., Danusso, F., Mantica, E., Mazzanti, G. and Moraglio, G., J. Am. Chem. Soc., 1955, 77(6): 1708CrossRef
  9.B枚hm, L.L., Angew. Chem. Int. Ed., 2003, 42(41): 5010CrossRef
  10.Brintzinger, H.H., Fischer, D., M眉lhaupt, R., Rieger, B. and Waymouth, R.M., Angew. Chem. Int. Ed., 1995, 34(11): 1143CrossRef
  11.Alt, H.G. and K枚ppl, A., Chem. Rev., 2000, 100(4): 1205CrossRef
  12.Kaminsky, W. and Laban, A., Appl. Catal. A: Gen., 2001, 222: 47CrossRef
  13.Gates, D.P, Svejda, S.A., O帽ate, E., Killian, C.M., Johnson, L.K., White, P.S. and Broohart, M., Macromolecules, 2000, 33(7): 2320CrossRef
  14.Helld枚rfer, M., Backhaus, J. and Alt, H.G., Inorg. Chim. Acta, 2003, 351: 34CrossRef
  15.Rose, J.M., Cherian, A.E. and Coates, G.W., J. Am. Chem. Soc., 2006, 128(13): 4186CrossRef
  16.Liu, H., Zhao, W.Z., Hao, X., Redshaw, C., Huang, W. and Sun, W.H., Organometallics, 2011, 30(8): 2418CrossRef
  17.Guan, Z., Cotts, P.M., McCord, E.F. and McLain, S.J., Science, 1999, 283: 2059CrossRef
  18.Tempel, D.J., Johnson, L.K., Huff, R.L., White, P.S. and Brookhart, M., J. Am. Chem. Soc., 2000, 122(28): 6686CrossRef
  19.Schleis, T., Spaniol, T.P., Okuda, J., Heinemann, J. and Mulhaupt, R., J. Organomet. Chem., 1998, 569: 159CrossRef
  20.Marques, M.M., Fernandes, S., Correia, S.G., Ascenso, J.R., Caroco, S., Gomes, P.T., Mano, J., Pereira, S.G., Nunes, T., Dias, A.R., Rausch, M.D. and Chien, J.C.W., Macromol. Chem. Phys., 2000, 201(17): 2464CrossRef
  21.Correia, S.G., Marques, M.M., Ascenso, J.R., Ribeiro, A.F.G., Gomes, P.T., Dias, A.R., Blais, M., Rausch, M.D. and Chien, J.C.W., J. Polym. Sci., Part A: Polym. Chem., 1999, 37(14): 2471CrossRef
  22.Fernandes, S., Marques, M.M., Correia, S.G., Mano, J. and Chien, J.C.W., Macromol. Chem. Phys., 2000, 201(17): 2566CrossRef
  23.Yuan, J. and Lu, S., Organometallics, 2001, 20(13): 2697CrossRef
  24.Helld枚rfer, M., Backhaus, J. and Alt, H.G., Inorg. Chim. Acta, 2003, 351: 34CrossRef
  25.Popeney, C. and Guan, Z., Organometallics, 2005, 24(6): 1145CrossRef
  26.Du, L., Wu, Z., Wu, Q., Jiang, C. and Piao, L., Chin. J. Catal., 2011, 32(3): 490
  27.Kundu, A. and Buffin, B.P., Organometallics, 2000, 20(17): 3635CrossRef
  28.Buffin, B.P. and Kundu, A., Inorg. Chem. Commun., 2003, 6(6): 680CrossRef
  29.Maldanis, R.J., Wood, J.S., Chandrasekaran, A., Rausch, M.D. and Chien, J.C.W., J. Organomet. Chem., 2002, 645(1鈥?): 158CrossRef
  30.de Souza, C.G., de Souza, R.F. and Bernardo-Gusm茫o, K., Appl. Catal. A: Gen., 2007, 325(1): 87CrossRef
  31.Yue, E., Zhang, L., Xing, Q., Cao, X.P., Hao, X., Redshaw, C. and Sun, W.H., Dalton Trans., 2014, 43(2): 423CrossRef
  32.Killian, C.M., Johnson, L.K. and Brookhart, M., Organometallics, 1997, 16(10): 2005CrossRef
  33.Zou, H., Hu, S., Huang, H.H., Zhu, F.M. and Wu, Q., Eur. Polym. J., 2007, 43(9): 3882CrossRef
  34.Galland, G.B., de Souza, R.F., Mauler, R.S. and Nunes, F.F., Macromolecules, 1999, 32(5): 1620CrossRef
  35.Galland, G.B., Quijada, R., Rojas, R., Bazan, G.C. and Komon, Z.J.A., Maromolecules, 2002, 35(2): 339CrossRef
  
• 作者单位：Bing Liu (1)
  Meng-zhe Fang (1)
  Su-yun Jie 浠嬬礌浜?/a> (1)
  Zhi-yang Bu (1)
  Bo-Geng Li (1)
  
  1. State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, 310027, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Condensed Matter Physics
  Industrial Chemistry and Chemical Engineering
  Polymer Sciences
  Characterization and Evaluation of Materials
  
• 出版者：Chinese Chemical Society and Institute of Chemistry, CAS, co-published with Springer
• ISSN：1439-6203

文摘

A series of nickel(II) 伪-diimine complexes with strong electron-withdrawing carboxyl groups, having reactive hydrogen atoms, were prepared and used as precatalysts for ethylene oligomerization and/or polymerization. The influence of metal halides and ligand structure on the catalytic activity and properties of products was investigated. The results showed that nickel bromide was much more active than nickel chloride, and the substituents at the ortho-position of aryl ring had large influence on the properties of products. Therefore, the products ranging from liquid oligomers to polymers could be readily obtained by the variation of the substituents on the ligands and reaction conditions. Keywords 伪-Diimine Nickel Ethylene Oligomerization Polymerization