Dewatering of MNFC containing microfibrils and microparticles from soybean hulls: mechanical and transport properties of hybrid films

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• 作者：Ana Ferrer ; Carlos Salas ; Orlando J. Rojas
• 关键词：Soybean hulls ; Micro and nanofibrillar cellulose ; Film ; Water contact angle ; Young modulus
• 刊名：Cellulose
• 出版年：2015
• 出版时间：December 2015
• 年：2015
• 卷：22
• 期：6
• 页码：3919-3928
• 全文大小：1,010 KB
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• 作者单位：Ana Ferrer (1) (2)
  Carlos Salas (1)
  Orlando J. Rojas (1) (3)
  
  1. Department of Forest Biomaterials, North Carolina State University, Raleigh, NC, 27695, USA
  2. Department of Chemical Engineering, University of Cordoba, 14071, C贸rdoba, Spain
  3. Biobased Colloids and Materials Group (BiCMat), Department of Forest Products Technology and Centre of Excellence on 鈥淢olecular Engineering of Biosynthetic Hybrid Materials Research鈥?(HYBER), School of Chemical Technology, Aalto University, 00076, Aalto, Finland
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Bioorganic Chemistry
  Physical Chemistry
  Organic Chemistry
  Polymer Sciences
  
• 出版者：Springer Netherlands
• ISSN：1572-882X

文摘

Cellulosic microfibrils (SMF) and microparticles (SMP) extracted from soybean hulls were used in films and also combined with wood-based micro and nanofibrillar cellulose (MNFC) in hybrid systems. During film consolidation a remarkable reduction in water drainage was observed in the presence of SMF and SMP. The hybrid films displayed strength (elastic modulus and strength at rupture) and barrier performance similar to those of neat MNFC films, thus offering an option for reduced cost while keeping a performance from synergistic contributions of the components. Furthermore, dense films with low-porosity, a characteristics essential for barrier properties, can be easily produced by replacing up to 75 % of MNFC with SMF or SMP. Keywords Soybean hulls Micro and nanofibrillar cellulose Film Water contact angle Young modulus