Simplified THz Instrumentation for High-Field DNP-NMR Spectroscopy
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- 作者：Thorsten Maly (1) tmaly@bridge12.com
Jagadishwar R. Sirigiri (1) - 刊名：Applied Magnetic Resonance
- 出版年：2012
- 出版时间：July 2012
- 年：2012
- 卷：43
- 期：1-2
- 页码：181-194
- 全文大小：575.1 KB
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- ISSN：1613-7507
文摘
We present an alternate simplified concept to irradiate a nuclear magnetic resonance sample with terahertz (THz) radiation for dynamic nuclear polarization (DNP) experiments using the TE01 circular waveguide mode for transmission of the THz power and the illumination of the DNP sample by either the TE01 or TE11 mode. Using finite element method and 3D electromagnetic simulations we demonstrate that the average value of the transverse magnetic field induced by the THz radiation and responsible for the DNP effect using the TE11 or the TE01 mode are comparable to that generated by the HE11 mode and a corrugated waveguide. The choice of the TE11/TE01 mode allows the use of a smooth-walled, oversized waveguide that is easier to fabricate and less expensive than a corrugated waveguide required for transmission of the HE11 mode. Also, the choice of the TE01 mode can lead to a simplification of gyrotron oscillators that operate in the TE0n mode, by employing an on-axis rippled-wall mode converter to convert the TE0n mode into the TE01 mode either inside or outside of the gyrotron tube. These novel concepts will lead to a significant simplification of the gyrotron, the transmission line and the THz coupler, which are the three main components of a DNP system.