The Oxidative Precipitation of Thallium at Alkaline pH for Treatment of Mining Influenced Water

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• 作者：Morgan Davies ; Linda Figueroa ; Thomas Wildeman…
• 关键词：Permanganate ; Metals ; Acid rock drainage ; Acid mine drainage ; Alkaline precipitation
• 刊名：Mine Water and the Environment
• 出版年：2016
• 出版时间：March 2016
• 年：2016
• 卷：35
• 期：1
• 页码：77-85
• 全文大小：1,153 KB
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• 作者单位：Morgan Davies (1)
  Linda Figueroa (2)
  Thomas Wildeman (2)
  Charles Bucknam (3)
  
  1. Geomega, Boulder, CO, USA
  2. Colorado School of Mines, Golden, CO, USA
  3. Analytical Unlimited LLC, Parker, CO, USA
  
• 刊物类别：Earth and Environmental Science
• 刊物主题：Earth sciences
  Applied Geosciences
  Mineral Resources
  Structural Foundations and Hydraulic Engineering
  Soil Science and Conservation
  Waste Management and Waste Technology
  Waste Water Technology, Water Pollution Control, Water Management and Aquatic Pollution
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1616-1068

文摘

Thallium (Tl) may exceed regulatory limits in mining-influenced water (MIW) associated with processing cadmium, copper, gold, lead, and zinc ores. It is a toxic metal that is soluble over a wide pH range, resulting in both persistence in the environment and poor removal by conventional lime precipitation. This study evaluated the effect of potassium permanganate (KMnO₄) at alkaline pH on Tl removal from MIW in batch experiments. The oxidation of Tl+ to Tl3+ by KMnO₄ and subsequent Tl removal was explored at Tl concentrations of ≤1 mg/L in synthetic and actual MIW. In addition to Tl, the synthetic MIW contained ≈5 mg/L of Mn, while the actual MIW contained >10 mg/L of Al, Cu, Fe, Mn, and Zn and had a pH ≈ 2.5. Dissolved Tl <2 μg/L in synthetic MIW was achieved at a pH ≈ 9 (CaO addition) and ≥5 mg/L of KMnO₄. In the actual MIW, dissolved Tl <2 μg/L was achieved at pH ≈ 9 and ≥12 mg/L of KMnO₄. The Tl removal mechanism is complicated due to the presence of reduced Mn in the synthetic MIW and multiple metals in the actual MIW. However, effective Tl removal was achieved by adding KMnO₄ to synthetic and actual MIW at alkaline pH.