参考文献:1.J. Schneider, M. Matsuoka, M. Takeuchi, J. Zhang, Y. Horiuchi, M. Anpo, D.W. Bahnemann, Understanding TiO2 photocatalysis: mechanisms and materials. Chem. Rev. 114(19), 9919–9986 (2014)CrossRef 2.X. Chen, A. Selloni, Introduction: titanium dioxide (TiO2) nanomaterials. Chem. Rev. 114(19), 9281–9282 (2014)CrossRef 3.L. Sang, Y. Zhao, C. Burda, TiO2 nanoparticles as functional building blocks. Chem. Rev. 114(19), 9283–9318 (2014)CrossRef 4.J. Liao, L. Shi, S. Yuan, Y. Zhao, J. Fang, Solvothermal synthesis of TiO2 nanocrystal colloids from peroxotitanate complex solution and their photocatalytic activities. J. Phys. Chem. 113(43), 18778–18783 (2009) 5.S. Yuan, L. Yu, L. Shi, J. Wu, J. Fang, Y. Zhao, Highly ordered TiO2 nanotube array as recyclable catalyst for the sonophotocatalytic degradation of methylene blue. Catal. Commun. 10(8), 1188–1191 (2009)CrossRef 6.M.H. Zhang, L.Y. Shi, S. Yuan, Y. Zhao, J.H. Fang, Synthesis and photocatalytic properties of highly stable and neutral TiO2/SiO2 hydrosol. J. Colloid Interface Sci. 330, 113–118 (2009)CrossRef 7.M.R. Hoffmann, S.T. Martin, W. Choi, D.W. Bahnemann, Environmental applications of semiconductor photocatalysis. Chem. Rev. 95(1), 69–96 (1995)CrossRef 8.M. Nasir, Z. Xi, M. Xing, J. Zhang, F. Chen, B. Tian, S. Bagwasi, Study of synergistic effect of Ce- and S-Codoping on the enhancement of visible-light photocatalytic activity of TiO2. J. Phys. Chem. C 117(18), 9520–9528 (2013)CrossRef 9.S. Yuan, Q. Sheng, J. Zhang, F. Chen, M. Anpo, W. Dai, Synthesis of Pd nanoparticles in La-doped mesoporous titania with polycrystalline framework. Catal. Lett. 107(1–2), 19–24 (2006)CrossRef 10.L. Wu, F. Li, Y. Xu, J.W. Zhang, D. Zhang, G. Li, H. Li, Plasmon-induced photoelectrocatalytic activity of Au nanoparticles enhanced TiO2 nanotube arrays electrodes for environmental remediation. Appl. Catal. B Environ. 164, 217–224 (2015)CrossRef 11.H. Yamashita, Y. Nishida, S. Yuan, K. Mori, M. Narisawa, Y. Matsumura, T. Ohmichi, I. Katayama, Design of TiO2–SiC photocatalyst using TiC–SiC nano-particles for degradation of 2-propanol diluted in water. Catal. Today 120(2), 163–167 (2007)CrossRef 12.M. Zhang, S. Yuan, Z. Wang, Y. Zhao, L. Shi, Photoelectrocatalytic properties of Cu2+-doped TiO2 film under visible light. Appl. Catal. B Environ. 134–135, 185–192 (2013)CrossRef 13.J. Liu, Y. Zhao, L. Shi, S. Yuan, J. Fang, Z. Wang, M. Zhang, Solvothermal synthesis of crystalline phase and shape controlled Sn4+-doped TiO2 nanocrystals: effects of reaction solvent. ACS Appl. Mater. Interfaces 3(4), 1261–1268 (2011)CrossRef 14.Z. Li, B. Gao, G.Z. Chen, R. Mokaya, S. Sotiropoulos, G.L. Puma, Carbon nanotube/titanium dioxide (CNT/TiO2) core–shell nanocomposites with tailored shell thickness, CNT content and photocatalytic/photoelectrocatalytic properties. Appl. Catal. B Environ. 110, 50–57 (2011)CrossRef 15.R. Hou, S. Yuan, X. Ren, Y. Zhao, Z. Wang, M. Zhang, D. Li, L. Shi, Effects of acetyl acetone-typed co-adsorbents on the interface charge recombination in dye-sensitized solar cell photoanodes. Electrochim. Acta 154, 190–196 (2015)CrossRef 16.Y. Zhao, J. Liu, L. Shi, S. Yuan, J. Fang, Z. Wang, M. Zhang, Solvothermal preparation of Sn4+ doped anatase TiO2 nanocrystals from peroxo-metal-complex and their photocatalytic activity. Appl. Catal. B Environ. 103(3–4), 436–443 (2011)CrossRef 17.S. Wu, S. Yuan, L. Shi, Y. Zhao, J. Fang, Preparation, characterization and electrical properties of fluorine-doped tin dioxide nanocrystals. J. Colloid Interface Sci. 346(1), 12–16 (2010)CrossRef 18.F. Fabregat-Santiago, E.M. Barea, J. Bisquert, G.K. Mor, K. Shankar, C.A. Grimes, High carrier density and capacitance in TiO2 nanotube arrays induced by electrochemical doping. J. Am. Chem. Soc. 130, 11312–11316 (2008)CrossRef 19.L. Yu, Z.Y. Wang, L.Y. Shi, S. Yuan, Y. Zhao, J.H. Fang, W. Deng, Photoelectrocatalytic performance of TiO2 nanoparticles incorporated TiO2 nanotube arrays. Appl. Catal. B Environ. 113–114, 318–325 (2012)CrossRef 20.O. Carp, C.L. Huisman, A. Reller, Photoinduced reactivity of titanium dioxide. Prog. Solid State Chem. 32(1–2), 33–177 (2004)CrossRef 21.J. Li, L. Zheng, L. Li, Y. Xian, L. Jin, Fabrication of TiO2/Ti electrode by laser-assisted anodic oxidation and its application on photoelectrocatalytic degradation of methylene blue. J. Hazard. Mater. 139, 72–78 (2007)CrossRef
作者单位:Hualan Zhou (1) Jie Ge (2) Meihong Zhang (2) Shuai Yuan (2)
1. School of Medical Instrument and Food Engineering, University of Shanghai for Science and Technology, Shanghai, 200093, People’s Republic of China 2. Research Center of Nanoscience and Nanotechnology, Shanghai University, 99 Shangda Road, Shanghai, 200444, People’s Republic of China
Mesoporous composite films of titania (TiO2) and antimony-doped tin oxide (ATO) were prepared on titanium plate substrates from pastes by the doctor-blade method. The photoelectrochemical properties of the samples with different ATO contents were investigated by the degradation of methylene blue under UV light irradiation. It was found that the photocatalytic activity of TiO2 was significantly improved with the help of the introduction of ATO nanocrystals and a forward bias. The synergetic effect of ATO and bias was analyzed by electrochemical impedance spectra (EIS). The EIS analysis results demonstrated that the separation of photogenerated electron–hole pairs can be efficiently enhanced by introducing ATO nanoparticles and applying an external bias.