Glycerol steam reforming over Ni–Fe–Ce/Al2O3 catalyst for hydrogen production
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- 作者：Gwang Sub Go ; Hong Joo Lee ; Dong Ju Moon…
- 关键词：Glycerol steam reforming ; Ni ; based catalyst ; Hydrogen production ; Kinetics ; Power ; law method
- 刊名：Research on Chemical Intermediates
- 出版年：2016
- 出版时间：January 2016
- 年：2016
- 卷：42
- 期：1
- 页码：289-304
- 全文大小：1,186 KB
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Hong Joo Lee (2)
Dong Ju Moon (3)
Young Chul Kim (4)
1. Department of Chemical Engineering, Chonnam National University, 77 Youngbong-ro, Buk-gu, Gwangju, 500-757, Republic of Korea
2. Department of Bioenergy Science and Technology, Chonnam National University, 77 Youngbong-ro, Buk-gu, Gwangju, 500-757, Republic of Korea
3. Korea Institute of Science and Technology, Hwarangno 14-gil 5, Seongbuk-gu, Seoul, 136-791, Republic of Korea
4. Faculty of Applied Chemical Engineering and the Research Institute for Catalysis, Chonnam National University, 300 Yongbong-ro, Gwangju, 500-757, Republic of Korea - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Catalysis
Physical Chemistry
Inorganic Chemistry - 出版者：Springer Netherlands
- ISSN：1568-5675
文摘
In this study, we focused on the catalytic activity, stability, and kinetics of glycerol steam reforming (GSR) for the hydrogen production over Ni–Fe–Ce/Al2O3 catalyst. The GSR was investigated in a quartz fixed-bed reactor with an internal diameter of 6 mm under atmospheric pressure, 18.44–44.56 g h/mol weight of catalyst per molar flow rate of glycerol at the inlet (W cat/F AO ratio), 20 wt% glycerol solution concentration, and the temperature range 450–550 °C. Ni–Fe–Ce/Al2O3 catalyst was characterized by N2 physisorption [Brunauer–Emmett–Teller (BET) method], X-ray spectroscopy, temperature-programmed reduction with H2, temperature-programmed desorption of adsorbed CO2 (CO2-TPD), scanning electron microscopy, and thermogravimetric analysis. H2, CO2, CO and CH4 were the main gaseous products with the H2:CO2 ratio at roughly 2.00. The increase in the temperature and W cat/F AO ratio caused the expected increase in the glycerol conversion and H2 yield. All the kinetic parameters for the GSR were obtained in the kinetically controlled reaction regime. The experimental data using the power-law method indicate that the reaction order with respect to glycerol and the activation energy were 0.06 and 32.9 kJ/mol, respectively. Keywords Glycerol steam reforming Ni-based catalyst Hydrogen production Kinetics Power-law method