Prospects for petroleum mass spectrometry and chromatography

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• 作者：Chang Samuel Hsu (14896) (24896) (34896)
  Quan Shi (34896)
  
• 关键词：mass spectrometry ; petroleum ; FT ; ICR ; GC×GC ; APGC
• 刊名：SCIENCE CHINA Chemistry
• 出版年：2013
• 出版时间：July 2013
• 年：2013
• 卷：56
• 期：7
• 页码：833-839
• 全文大小：1100KB
• 参考文献：1. Hsu CS, Robinson PR. / Practical Advances in Petroleum Processing. New York: Springer, 2006 CrossRef
  2. Hsu CS. / Analytical Advances for Hydrocarbon Research. New York: Springer, 2003 CrossRef
  3. Kiser RW. / Introduction to Mass Spectrometry and Its Applications. Englewood Cliffs: Prentice-Hall, 1965
  4. Hsu CS, Drinkwater D. / GC/MS in the petroleum industry, in Current Practice of Gas Chromatography-Mass Spectrometry. Niessen WWA, Editor. New York: CRC, 2001, 55-4
  5. Qian K, Hsu CS. Molecular transformation in hydrotreating processes studied by on-line liquid chromatography/mass spectrometry. / Anal Chem, 1992, 64: 2327-333 CrossRef
  6. Qian K, Rodgers RP, Hendrickson CL, Emmett MR, Marshall AG. Reading chemical fine print: Resolution and identification of 3000 nitrogen-containing aromatic compounds from a single electrospray ionization Fourier transform ion cyclotron resonance mass spectrum of heavy petroleum crude oil. / Energ Fuel, 2001, 15: 492-98 CrossRef
  7. Qian K, Robbins WK, Hughey CA, Cooper HJ, Rodgers RP, Marshall AG. Resolution and identification of elemental compositions for more than 3000 crude acids in heavy petroleum by negative-ion micro-electrospray high-field Fourier transform ion cyclotron resonance mass spectrometry. / Energ Fuel, 2001, 15: 1505-511 CrossRef
  8. Marshall AG, Rodgers RP. Petroleomics: The next grand challenge for chemical analysis. / Acc Chem Res, 2004, 37: 53-9 CrossRef
  9. Rodgers RP, Schaub TM, Marshall AG. Petroleomics: MS returns to its roots. / Anal Chem, 2005, 77: 20A-7A CrossRef
  10. Hsu CS, Hendrickson CL, Rodgers RP, McKenna AM, Marshall AG. Petroleomics: Advanced molecular probe for petroleum heavy ends. / J Mass Spectrom, 2011, 46: 337-43 CrossRef
  11. Xian F, Hendrickson CL, Blakney GT, Beu SC, Marshall AG. Automated broadband phase correction of Fourier transform ion cyclotron resonance mass spectra. / Anal Chem, 2010, 82: 8807-812 CrossRef
  12. Purcell JM, Hendrickson CL, Rodgers RP, Marshall AG. Atmospheric pressure photoionization Fourier transform ion cyclotron resonance mass spectrometry for complex mixture analysis. / Anal Chem, 2006, 78: 5906-912 CrossRef
  13. Haapala M, Purcell JM, Saarela V, Franssila S, Rodgers RP, Hendrickson CL, Kotiaho T, Marshall AG, Kostiainen R. Microchip atmospheric pressure photoionization for analysis of petroleum by Fourier transform ion cyclotron resonance mass spectrometry. / Anal Chem, 2009, 81: 2799-803 CrossRef
  14. McKenna AM, Purcell JM, Rodgers RP, Marshall AG. Identification of vanadyl porphyrins in a heavy crude oil and raw asphaltene by atmospheric pressure photoionization Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry. / Energ Fuel, 2009, 23: 2122-128 CrossRef
  15. Hsu CS, Binkley J, Mason M, Lu J, Shi Q. Accurate quantitation of petroleum biomarkers. / Prepr Pap-Am Chem Soc Div Energy Fuels Chem, 2012, 57: 997-98
  16. Stevens D, Shi Q, Hsu CS. Novel analytical technique for petroleum biomarker analysis. / Energ Fuel, 2013, 27: 167-71 CrossRef
  17. Hsu CS, Shi Q. Petroleum mass spectrometry: Past, present and future. in / Heavy Oil Forum: International Conference on Chemistry of Heavy Petroleum Fractions and Its Impacts on Refining Processes. Beijing, 2012
  18. Hsu CS, Qian K, Chen YC. An innovative approach to data analysis in hydrocarbon characterization by on-line liquid chromatography-mass spectrometry. / Anal Chim Acta, 1992, 264: 79-9 CrossRef
  19. Zhang L, Xu Z, Shi Q, Sun X, Zhang N, Zhang Y, Chung KH, Xu C, Zhao S. Molecular characterization of polar heteroatom species in Venezuela Orinoco petroleum vacuum residue and its supercritical fluid extraction subfractions. / Energ Fuel, 2012, 26: 5795-803 CrossRef
  
• 作者单位：Chang Samuel Hsu (14896) (24896) (34896)
  Quan Shi (34896)
  
  14896. Petro Bio Oil Consulting, Tallahassee, FL, 32312, USA
  24896. Department of Chemical and Biomedical Engineering, Florida State University, Tallahassee, FL, 32310, USA
  34896. State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing, 102249, China
  

文摘

Several recently developed analytical techniques, based on high-end mass spectrometry and chromatography, for dealing with challenges in petroleum characterization are reported. Folded flight path time-of-flight mass spectrometry provides resolving power up to 100000, enabling accurate mass measurement for molecular formula determination with high confidence. Atmospheric pressure chemical ionization (APCI) can be used in both gas chromatography (GC, as APGC) and liquid chromatography (LC) for analyzing non-polar hydrocarbons as well as polar compounds. The improvement in chromatography facilitates the mass spectrometric analysis through online coupling. Comprehensive two-dimensional gas chromatography (GC×GC) resolves overlapping components, rendering accurate identification and quantitation. Supercritical fluid extraction has been developed as an alternative method to replace traditional solvent extraction methods and eliminate the use of large volumes of solvents that can be harmful to health and environment. Supercritical fluid chromatography (SFC) has been developed as a convergence of GC and LC chromatographic techniques. The use of SFC for heavy oils and residua has been demonstrated. Prospective developments in the use of mass spectrometric and chromatographic methods for petroleum characterization are also described.