A review of semi-rigid, stilbene-containing alternating copolymers
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- 作者：Alice M. Savage ; Xu Zhou ; Jing Huang ; S. R. Turner
- 关键词：Stilbene ; Alternating copolymers ; Copolymerization ; Maleic anhydride ; Maleimides
- 刊名：Applied Petrochemical Research
- 出版年：2015
- 出版时间：March 2015
- 年：2015
- 卷：5
- 期：1
- 页码：27-33
- 全文大小：449 KB
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- ISSN：2190-5533
文摘
The synthesis and properties of sterically congested, stilbene-containing alternating copolymers are reviewed. Persistence lengths (2-?nm) determined by size exclusion chromatography and small angle X-ray scattering techniques show that these are semi-rigid copolymers. Fully characterized polyanions and polyampholytes, prepared from organic-soluble precursors were studied, along with their respective salt and pH response behavior resulting from the semi-rigid polymer backbone. The solid-state characterization from these studies reveals a high degree of hindered rotation along the polymer backbone. The contorted structure and the hindered rotation of the polymer backbone generate inefficient chain packing, which leads to an increase of nanoporosity and higher surface areas. The semi-rigid stilbene-containing copolymers are a new class of copolymers where the increased polymer backbone rigidity leads to a wide range of polymer properties not attained with flexible polymers.