Kinetic and Mechanistic Elucidation of the Formation Reaction of 3,4,5-Substituted Furan-2(5H)-Ones in Formic Acid as the Solvent

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• 作者：Sayyed Mostafa Habibi-Khorassani ; Mehdi Shahraki…
• 关键词：Kinetics ; Reaction mechanism ; Furan ; 2(5H) ; ones ; Activation parameters
• 刊名：Journal of Solution Chemistry
• 出版年：2015
• 出版时间：November 2015
• 年：2015
• 卷：44
• 期：11
• 页码：2154-2166
• 全文大小：1,195 KB
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• 作者单位：Sayyed Mostafa Habibi-Khorassani (1)
  Mehdi Shahraki (1)
  Maryam Dehdab (1)
  Mohammad Ali Poorshamsoddin (1)
  
  1. Department of Chemistry, Faculty of Science, University of Sistan and Baluchestan, P. O. Box 98135-674, Zahedan, Iran
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Physical Chemistry
  Industrial Chemistry and Chemical Engineering
  Geochemistry
  Oceanography
  Inorganic Chemistry
  Condensed Matter
  
• 出版者：Springer Netherlands
• ISSN：1572-8927

文摘

For the first time, kinetics and mechanism of a one-pot multicomponent reaction between 4-methyl aniline 1 and diethyl acetylenedicarboxylate 2 with benzaldehyde 3 has been investigated spectroscopically in formic acid. The reaction followed second-order kinetics overall. Also, partial orders with respect to 4-methyl aniline 1, diethyl acetylenedicarboxylate 2 and benzaldehyde 3 are one, one and zero, respectively. Considering the kinetic results, a mechanism was proposed involving four steps. Furthermore, thermodynamic activation parameters and also kinetic values were obtained and examined at the various temperatures and solvents. The results show that the first step of the reaction mechanism is a rate-determining step.