刊名:Protection of Metals and Physical Chemistry of Surfaces
出版年:2016
出版时间:March 2016
年:2016
卷:52
期:2
页码:232-237
全文大小:569 KB
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作者单位:S. N. Stepanenko (1) A. R. Tameev (1) M. G. Tedoradze (1) A. Yu. Chernyad’ev (1) A. V. Vannikov (1) A. Yu. Tsivadze (1)
1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, bldg 4, Moscow, 199071, Russia
刊物类别:Chemistry and Materials Science
刊物主题:Chemistry Tribology, Corrosion and Coatings Materials Science Metallic Materials Inorganic Chemistry Industrial Chemistry and Chemical Engineering Characterization and Evaluation Materials
出版者:MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
ISSN:2070-206X
文摘
This work studies the role of a cathodic TiO x buffer layer in operation of a photovoltaic organic solar cell (OSC) based on a photoactive layer with a bulk heterojunction. Using a liquid solution to obtain a TiO x layer is of current interest for simplification of process technologies of successive formation of OSC layers. It is found that the optimum thickness of the TiO x layer is 10 nm; at this thickness, the efficiency of the OSC reaches the value of 4.36%. The effect of air oxygen on the OSC samples is studied and it is found that samples with a TiO x buffer layer undergo degradation to a lesser extent as compared to the samples with no such layer. The effect of oxygen on operation of the photovoltaic device is discussed.