In situ polymerized poly(butylene succinate-co-ethylene terephthalate)/hydroxyapatite nanocomposite with adjusted thermal, mechanical and hydrolytic degradation properties

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• 作者：Hadi Shirali ; Mehdi Rafizadeh ; Faramarz Afshar Taromi
• 关键词：copolyester ; nanocomposite ; poly(butylene succinate ; co ; ethylene terephthalate) ; nano hydroxyapatite ; degradability
• 刊名：Macromolecular Research
• 出版年：2016
• 出版时间：October 2016
• 年：2016
• 卷：24
• 期：10
• 页码：900-908
• 全文大小：875 KB
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Physical Chemistry
  Polymer Sciences
  Characterization and Evaluation of Materials
  Soft and Granular Matter, Complex Fluids and Microfluidics
  Nanochemistry
  Nanotec
  
• 出版者：The Polymer Society of Korea, co-published with Springer
• ISSN：2092-7673
• 卷排序：24

文摘

New nanocomposites of poly(butylene succinate-co-ethylene terephthalate)/nano hydroxyapatite were synthesized using two-step in situ polycondensation. The composition, microstructure, morphology and dispersion of nanoparticles in the nanocomposites were studied using proton nuclear magnetic resonance (1H NMR), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). It was found that presence of nano hydroxyapatite catalyzes the reaction and there is a chemical bond between nanoparticles and polymer which leads to a good particle dispersion but it doesn’t affect molecular sequence length. Nanocomposites’ thermal properties evaluated by differential scanning calorimetry (DSC) and X-ray diffraction (XRD), showed that crystallinity and crystallite size slightly decrease with the nanoparticles weight fraction. 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Jabbari, Polymer, 55, 3894 (2014).CrossRefGoogle ScholarCopyright information© The Polymer Society of Korea and Springer Sciene+Business Media Dordrecht 2016Authors and AffiliationsHadi Shirali1Mehdi Rafizadeh1Email authorFaramarz Afshar Taromi11.Department of Polymer Engineering and Color TechnologyAmirkabir University of TechnologyTehranIran About this article CrossMark Print ISSN 1598-5032 Online ISSN 2092-7673 Publisher Name The Polymer Society of Korea About this journal Reprints and Permissions Article actions function trackAddToCart() { var buyBoxPixel = new webtrekkV3({ trackDomain: "springergmbh01.webtrekk.net", trackId: "196033507532344", domain: "link.springer.com", contentId: "springer_com.buybox", product: "10.1007/s13233-016-4131-4_ In situ polymerized poly(butylene", productStatus: "add", productCategory : { 1 : "ppv" }, customEcommerceParameter : { 9 : "link.springer.com" } }); buyBoxPixel.sendinfo(); } function trackSubscription() { var subscription = new webtrekkV3({ trackDomain: "springergmbh01.webtrekk.net", trackId: "196033507532344", domain: "link.springer.com", contentId: "springer_com.buybox" }); subscription.sendinfo({linkId: "inst. subscription info"}); } window.addEventListener("load", function(event) { var viewPage = new webtrekkV3({ trackDomain: "springergmbh01.webtrekk.net", trackId: "196033507532344", domain: "link.springer.com", contentId: "SL-article", product: "10.1007/s13233-016-4131-4_ In situ polymerized poly(butylene", productStatus: "view", productCategory : { 1 : "ppv" }, customEcommerceParameter : { 9 : "link.springer.com" } }); viewPage.sendinfo(); }); Log in to check your access to this article Buy (PDF)EUR 34,95 Unlimited access to full article Instant download (PDF) Price includes local sales tax if applicable Find out about institutional subscriptions Export citation .RIS Papers Reference Manager RefWorks Zotero .ENW EndNote .BIB BibTeX JabRef Mendeley Share article Email Facebook Twitter LinkedIn Cookies We use cookies to improve your experience with our site. 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