Double Stranded Helical Organo-lead 3D-Supramolecular Coordination Polymer Containing Copper Cyanide and Phenanthroline Ligand as Antimicrobial Agent

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• 作者：Safaa Eldin H. Etaiw ; Safaa N. Abdou
• 关键词：Organo ; lead ; Cuprous cyanide ; 1 ; 10 ; Phenanthroline ; Crystal structure ; helical structure ; Spectra ; Antimicrobial activity
• 刊名：Journal of Inorganic and Organometallic Polymers and Materials
• 出版年：2016
• 出版时间：January 2016
• 年：2016
• 卷：26
• 期：1
• 页码：117-126
• 全文大小：1,326 KB
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• 作者单位：Safaa Eldin H. Etaiw (1)
  Safaa N. Abdou (1) (2)
  
  1. Faculty of Science, Department of Chemistry, University of Tanta, Tanta, Egypt
  2. Chemistry Department, Faculty of Education and Science (Khourma), University of Taif, Taif, Saudi Arabia
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Inorganic Chemistry
  Organic Chemistry
  Polymer Sciences
  
• 出版者：Springer New York
• ISSN：1574-1451

文摘

The supramolecular coordination polymer (SCP) [Cu(CN)₂(Me₃Pb)phen]; 1 is formed by self-assembly of K₃[Cu(CN)₄], Me₃PbCl and 1,10-phenanthroline (phen) ligand at ambient conditions. The copper center is coordinated to two ordered cyanide ligands and two nitrogen atoms of the phen ligand forming distorted tetrahedral configuration. The structure of 1 consists of repeating units of the tetrahedral Cu(phen)(CN)₂ fragments connected by the (Me₃Pb)+ cations forming1-D helical chains. The 1-D helical chains are arranged in a unique way to construct a right-helical and a left-helical chain creating a double-helical 3-D network arranged in a unique A···A···A fashion. H-bonds and π–π stacking play an important role in stabilizing the structure of 1. IR, 1H-NMR, electronic and luminescence spectra as well as thermal analysis are also investigated. The SCP 1 has high antimicrobial activity against E. coli and S. aureus and it also exhibits good activity against the fungal strains, C. albicans and A. Niger. The results of growth inhibiting effect indicated that the inhibitory effect is increased with an increase in concentration of the SCP 1. Keywords Organo-lead Cuprous cyanide 1,10-Phenanthroline Crystal structure, helical structure Spectra Antimicrobial activity