Assessment of the conventional molybdenum-blue and magnesium-induced coprecipitation procedures in phosphorus measurement in various aquatic environments

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• 作者：Sumei Liu (1)
  Yingfei Zhao (1)
  Jingling Ren (1)
  Jing Zhang (1) (2)
  San Sun (1)
  Jie Jin (1)
  Guiling Zhang (1)
  
• 关键词：phosphorus ; magnesium ; induced coprecipitation ; conventional blue phosphomolybic acid assay ; various aquatic environments
• 刊名：Acta Oceanologica Sinica
• 出版年：2010
• 出版时间：January 2010
• 年：2010
• 卷：29
• 期：1
• 页码：42-51
• 全文大小：447KB
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• 作者单位：Sumei Liu (1)
  Yingfei Zhao (1)
  Jingling Ren (1)
  Jing Zhang (1) (2)
  San Sun (1)
  Jie Jin (1)
  Guiling Zhang (1)
  
  1. Key Laboratory of Marine Chemistry Theory and Technology Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of Qingdao, Qingdao, 266100, China
  2. State Key Laboratory of Estuarine and Coastal Research, East China Normal University, Shanghai, 200062, China
  
• ISSN：1869-1099

文摘

Phosphorus (P) is an essential nutrient utilized by all organisms for energy transport and growth. Both the conventional molybdenum-blue method and the magnesium-induced coprecipitation (MAGIC) procedures were applied for the measurement of dissolved inorganic phosphorus (DIP) and total dissolved phosphorus (TDP) in more than 840 water samples collected between 2003 and 2005, including seawater (the Huanghai Sea, the East China Sea, and the northern South China Sea), water from rivers and estuaries (the Changjiang, the Huanghe, and the major rivers emptying into the Jiaozhou Bay), groundwater (in the drainage basin surrounding the Jiaozhou Bay), rainwater, and aquaculture water samples. The MAGIC method allows the investigation of phosphorus distributions and cycling for systems in which DIP is below the detection limits of conventional methods. Comparison between the two methods demonstrated that the concentrations obtained with both methods were significantly correlated. The differences of DIP and TDP concentrations measured with the two methods were higher when the concentrations of DIP and TDP were lower, implying the lower reproducibility at low concentrations. The concentration differences increase with the increase in the proportion of DOP in TDP, which indicates that the discrepancy of DIP concentrations measured with the two methods increases when the DOP concentration is high. The discrepancies indicated that the composition of P compounds differs depending on sample sources and water type; it would be useful to infer the presence of different phosphorus compound pools from differences between the two methods. This study indicates the potential presence of a pool of alkaline-labile compounds for samples from rainwater and rivers and estuaries surrounding the Jiaozhou Bay; the potential presence of acid-labile compounds that were adsorbed by Mg(OH)2 for samples from the Changjiang Estuary, Huanghai Sea, East China Sea, and groundwater; the potential presence of a substantial pool of acid-labile compounds that were not adsorbed by Mg(OH)2 for samples from the Huanghe Estuary, aquaculture water, the East China Sea algal bloom water, and the northern South China Sea.