Study of the supramolecular interactions of carboxylic acids used as versatile ligands in coordination chemistry
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- 作者：C. C. Corrêa ; F. M. Scaldini ; F. C. Machado…
- 关键词：supramolecular arrangement ; carboxylate ligands ; X ; ray diffraction
- 刊名：Journal of Structural Chemistry
- 出版年：2016
- 出版时间：November 2016
- 年：2016
- 卷：57
- 期：6
- 页码：1235-1242
- 全文大小：
- 刊物类别：Chemistry and Materials Science
- 刊物主题：Inorganic Chemistry; Physical Chemistry; Atomic, Molecular, Optical and Plasma Physics; Atomic/Molecular Structure and Spectra; Solid State Physics;
- 出版者：Pleiades Publishing
- ISSN：1573-8779
- 卷排序：57
文摘
Carboxylate ligands are very versatile because they can adopt different coordination modes towards metal cations, such as monodentate, bidentate-chelate, bidentate bridging and monoatomic bridging. Because of this versatility, these ligands have been widely used in coordination chemistry. In this study the three dimensional structure of the crystal arrangement of 2,5-thiophenedicarboxylic (H2TPD), trans-3-(3- pyridyl)acrylic (HPYA), and 4,4′-sulfonyldibenzoic (H2SFD) acids are determined in order to investigate their supramolecular properties for coordination polymers and metal-organic framework (MOF) constructions.