Polymer electrolytes based on polycarbonates and their electrochemical and thermal properties

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• 作者：Masashi Matsumoto (1)
  Takahiro Uno (1)
  Masataka Kubo (2)
  Takahito Itoh (1)
  
• 关键词：Polymer synthesis ; Polymer electrolytes ; Polymer battery application
• 刊名：Ionics
• 出版年：2013
• 出版时间：April 2013
• 年：2013
• 卷：19
• 期：4
• 页码：615-622
• 全文大小：352KB
• 参考文献：1. MacCallum JR, Vincent CA (1987 and 1989) Polymer electrolyte reviews 1 and 2. Elsevier, London
  2. Bruce PG (1995) Solid state electrochemistry. Cambridge University Press, Cambridge
  3. Scrosati B (1993) Applications of electroactive polymers. Chapman and Hall, London CrossRef
  4. Gray FM (1997) Polymer electrolytes. The Royal Society of Chemistry, London
  5. Gray FM (1991) Solid polymer electrolytes: fundamentals and technological applications. VCH Publishers, New York
  6. Liplowski J, Ross PN (1994) The electrochemistry of novel materials. VHC Publishers, New York
  7. Croce F, Appetecchi GB, Persi L, Scrosati B (1998) Nature 394:456 CrossRef
  8. Nishimoto A, Watanabe M, Ikeda Y, Kojiya S (1998) Electrochim Acta 43:1177 CrossRef
  9. Itoh T, Hirata N, Wen Z, Kubo M, Yamamoto O (2001) J Power Sources 97鈥?8:637 CrossRef
  10. Tominaga Y, Izumi Y, Kwark GH, Asai S, Sumita H (2003) Macromolecules 36:8766 CrossRef
  11. Angell CA, Liu C, Sanchez E (1993) Nature 362:137 CrossRef
  12. Forsyth M, Jiazeng S, MacFarlane DR (2000) Electrochim Acta 45:1249 CrossRef
  13. Every HA, Zhou F, Forsyth M, MacFarlane DR (1998) Electrochem Acta 43:1465 CrossRef
  14. Yamamoto T, Inami M, Kanbara T (1994) Chem Mater 6:44 CrossRef
  15. Wei X, Shriver DF (1998) Chem Mater 10:2307 CrossRef
  16. Zhang S, Cheng Z, Ku K, Angell CA (2000) Electrochim Acta 45:1229 CrossRef
  17. Mitsuda H, Uno T, Kubo M, Itoh T (2006) Polym Bull 57:313 CrossRef
  18. Tominaga Y, Shimomura T, Nakamura M (2010) Polymer 50:4295 CrossRef
  19. Nakamura M, Tominaga Y (2011) Electrochim Acta 57:36 CrossRef
  20. Jungk SJ, Moore JA, Gandour RD (1983) J Org Chem 48:1116 CrossRef
  21. Evans J, Vincent CA, Bruce PG (1987) Polymer 28:2824 CrossRef
  22. Bruce PG, Vincent CA (1987) J Electroanal Chem 225:1 CrossRef
  23. Matsumoto M, Uno T, Kubo M, Itoh T (2011) J Mater Sci Eng A 1:607
  24. Lauter U, Meyer H, Wegner G (1997) Macromolecules 30:2092 CrossRef
  25. Vogel H (1921) Phys Z 22:645
  26. Tammann VG, Hesse WZ (1926) Anorg Allg Chem 156:245 CrossRef
  27. Fulcher GS (1925) J Am Ceram Soc 8:339 CrossRef
  28. Allcock HR, Kellam EC (2003) Solid State Ionics 156:401 CrossRef
  29. Saboungi ML, Price DL, Mao CM, Perea RF, Borodin O, Smith GD, Michel A, Howells WS (2002) Solid State Ionics 147:225 CrossRef
  30. Borodin O, Smith GD (1998) Macromolecules 31:8396 CrossRef
  31. Macglashn GS, Andreev YG, Bruce PG (1999) Nature 398:792 CrossRef
  32. Armand M, Gorecki W, Andreani R (1990) In: Scrosati B (ed) Second international symposium on polymer electrolytes. Elsevier, London
  33. Doeff MM, Georen P, Qiao J, Kerr J, De Jonghe LC (1999) J Electrochem Soc 146:2024 CrossRef
  34. Ferry A, Doeff MM, De Jonghe LC (1998) J Electrochem Soc 145:1586 CrossRef
  
• 作者单位：Masashi Matsumoto (1)
  Takahiro Uno (1)
  Masataka Kubo (2)
  Takahito Itoh (1)
  
  1. Division of Chemistry for Materials, Graduate School of Engineering, Mie University, 1577 Kurimamachiya-cho, Tsu, Mie, 514-8507, Japan
  2. Graduate School of Regional Innovation Studies, Mie University, 1577 Kurimamachiya-cho, Tsu, Mie, 514-8507, Japan
  
• ISSN：1862-0760

文摘

Polycarbonates (4a鈥揹) with various side chain lengths were synthesized by the reaction of 1,4-bis(hydroxyethoxy)benzene derivatives and triphosgene in the presence of pyridine. The polymer electrolytes composed of 4a鈥揹 with lithium bis(trifluoromethanesulfonyl)imide (LiN(SO2CF3)2, LiTFSI) were prepared, and their ionic conductivities and thermal and electrochemical properties were investigated. 4d-Based polymer electrolyte showed the highest ionic conductivity values of 1.0鈥壝椻€?0鈭?鈥塖/cm at 80聽掳C and 1.5鈥壝椻€?0鈭?鈥塖/cm at 30聽掳C, respectively, at the [LiTFSI]/[repeating unit] ratio of 1/2. Ionic conductivities of these polycarbonate-based polymer electrolytes showed the tendency of increase with increasing the chain length of oxyethylene moieties as side chains, suggestive of increased steric hindrance by side chains. Unique properties were observed for the 4a(n鈥?鈥?)-based polymer electrolyte without an oxyethylene moiety. All of polycarbonate-based polymer electrolytes showed good electrochemical and thermal stabilities as polymer electrolytes for battery application.