Magnetic molecular imprint-based extraction of sulfonylurea herbicides and their determination by capillary liquid chromatography

详细信息    查看全文

• 作者：María Jesús Lerma-García (1) (2)
  Mohammed Zougagh (2) (3)
  Angel Ríos (1) (2)
  
• 关键词：Magnetic molecularly imprinted polymer ; Extraction ; Capillary liquid chromatography ; Sulfonylurea herbicides ; Environmental water samples
• 刊名：Microchimica Acta
• 出版年：2013
• 出版时间：6 - April 2013
• 年：2013
• 卷：180
• 期：5
• 页码：363-370
• 全文大小：291KB
• 参考文献：1. Sarmah AK, Sabadie J (2002) Hydrolysis of sulfonylurea herbicides in soils and aqueous solutions: a review. J Agric Food Chem 50:6253-265 CrossRef
  2. Weber JB, Warren RL, Swain LR, Yelverton FH (2007) Physicochemical property effects of three herbicides and three soils on herbicide mobility in field lysimeters. Crop Prot 26:299-11 CrossRef
  3. Barros JFC, Basch G, de Carvalho M (2007) Effect of reduced doses of a post-emergence herbicide to control grass and broad-leaved weeds in no-till wheat under Mediterranean conditions. Crop Prot 26:1538-545 CrossRef
  4. Blair AM, Martin TD (1988) A review of the activity, fate and mode of action of sulfonylurea herbicides. Pestic Sci 22:195-19 CrossRef
  5. Klaffenbach P, Holland PT (1993) Analysis of sulfonylurea herbicides by gas–liquid chromatography III—mass spectrometry and multiresidue determination. Biol Mass Spectrom 22:565-78 CrossRef
  6. Quesada-Molina C, Olmo-Iruela M, García-Campa?a AM (2010) Trace determination of sulfonylurea herbicides in water and grape samples by capillary zone electrophoresis using large volume sample stacking. Anal Bioanal Chem 397:2593-601 CrossRef
  7. Zhang S, Yin X, Yang Q, Wang C, Wang Z (2011) Determination of some sulfonylurea herbicides in soil by a novel liquid-phase microextraction combined with sweeping micellar electrokinetic chromatography. Anal Bioanal Chem 401:1071-081 CrossRef
  8. Yang L, Zhao X, Zhou J (2010) Selective enrichment and determination of nicosulfuron in water and soil by a stir bar based on molecularly imprinted polymer coatings. Anal Chim Acta 670:72-7 CrossRef
  9. Zhou Q, Xiao J, Wang W (2007) Comparison of multiwalled carbon nanotubes and a conventional absorbent on the enrichment of sulfonylurea herbicides in water samples. Anal Sci 23:189-92 CrossRef
  10. Polati S, Bottaro M, Frascarolo P, Gosetti F, Gianotti V, Gennaro MC (2006) HPLC-UV and HPLC-MS ^{/ n} multiresidue determination of amidosulfuron, azimsulfuron, nicosulfuron, rimsulfuron, thifensulfuron methyl, tribenuron methyl and azoxystrobin in surface waters. Anal Chim Acta 579:146-51 CrossRef
  11. She Y, Cao W, Shi X, Lv X, Liu J, Wang R, Jin F, Wang J, Xiao H (2010) Class-specific molecularly imprinted polymers for the selective extraction and determination of sulfonylurea herbicides in maize samples by high-performance liquid chromatography–tandem mass spectrometry. J Chromatogr B 878:2047-053 CrossRef
  12. Di Corcia A, Crescenzi C, Samperi R, Scappaticcio L (1997) Trace analysis of sulfonylurea herbicides in water: extraction and purification by a carbograph 4 cartridge, followed by liquid chromatography with UV Detection, and confirmatory analysis by an electrospray/mass detector. Anal Chem 69:2819-826 CrossRef
  13. Kang S, Chang N, Zhao Y, Pan C (2011) Development of a method for the simultaneous determination of six sulfonylurea herbicides in wheat, rice, and corn by liquid chromatography—tandem mass spectrometry. J Agric Food Chem 59:9776-781 CrossRef
  14. Bouri M, Gurau M, Salghi R, Cretescu I, Zougagh M, Ríos A (2012) Ionic liquids supported on magnetic nanoparticles as a sorbent preconcentration material for sulfonylurea herbicides prior to their determination by capillary liquid chromatography. Anal Bioanal Chem 404:1529-538 CrossRef
  15. Yan C, Zhang B, Liu W, Feng F, Zhao Y, Du H (2011) Rapid determination of sixteen sulfonylurea herbicides in surface water by solid phase extraction cleanup and ultra-high-pressure liquid chromatography coupled with tandem mass spectrometry. J Chromatogr B 879:3484-489 CrossRef
  16. Eremin SA, Ryabova IA, Yakovleva JN, Yazynina EV, Zherdev AV, Dzantiev BB (2002) Development of a rapid, specific fluorescence polarization immunoassay for the herbicide chlorsulfuron. Anal Chim Acta 468:229-36 CrossRef
  17. Schedl M, Wilharm G, Achatz S, Kettrup A, Niessner R, Knopp D (2001) Monitoring polycyclic aromatic hydrocarbon metabolites in human uUrine: extraction and purification with a sol—gel glass immunosorbent. Anal Chem 73:5669-676 CrossRef
  18. Spivak DA (2005) Optimization, evaluation, and characterization of molecularly imprinted polymers. Adv Drug Del Rev 57:1779-794 CrossRef
  19. Lv Y, Lin Z, Fena W, Zhou X, Tan T (2007) Selective recognition and large enrichment of dimethoate from tea leaves by molecularly imprinted polymers. Biochem Eng J 36:221-29 CrossRef
  20. Chapuis F, Pichon V, Lanza F, Sellergren B, Hennion M-C (2004) Retention mechanism of analytes in the solid-phase extraction process using molecularly imprinted polymers: Application to the extraction of triazines from complex matrices. J Chromatogr B 804:93-01 CrossRef
  21. Lai EPC, Wu SG (2003) Molecularly imprinted solid phase extraction for rapid screening of cephalexin in human plasma and serum. Anal Chim Acta 481:165-74 CrossRef
  22. Hu S-G, Li L, He X-W (2005) Comparison of trimethoprim molecularly imprinted polymers in bulk and in sphere as the sorbent for solid-phase extraction and extraction of trimethoprim from human urine and pharmaceutical tablet and their determination by high-performance liquid chromatography. Anal Chim Acta 537:215-22 CrossRef
  23. Baggiani C, Baravalle P, Giraudi G (2007) Molecularly imprinted solid-phase extraction method for the high-performance liquid chromatographic analysis of fungicide pyrimethanil in wine. J Chromatogr A 1141:158-64 CrossRef
  24. Peng Y, Xie Y, Luo J, Nie L, Chen Y, Chen L, Du S, Zhang Z (2010) Molecularly imprinted polymer layer-coated silica nanoparticles toward dispersive solid-phase extraction of trace sulfonylurea herbicides from soil and crop samples. Anal Chim Acta 674:190-00 CrossRef
  25. Zhu Q-Z, Degelmann P, Niessner R, Knopp D (2002) Selective trace analysis of sulfonylurea herbicides in water and soil samples based on solid-phase extraction using a molecularly imprinted polymer. Environ Sci Technol 36:5411-420 CrossRef
  26. Zhu Q-Z, Haupt K, Knopp D, Niessner R (2002) Molecularly imprinted polymer for metsulfuron-methyl and its binding characteristics for sulfonylurea herbicides. Anal Chim Acta 468:217-27 CrossRef
  27. He J, Wang S, Fang G, Zhu H, Zhang Y (2008) Molecularly Imprinted polymer online solid-phase extraction coupled with high-performance liquid chromatography—UV for the determination of three sulfonamides in pork and chicken. J Agric Food Chem 56:2919-925 CrossRef
  28. Luo X, Zhan Y, Huang Y, Yang L, Tu X, Luo S (2011) Removal of water-soluble acid dyes from water environment using a novel magnetic molecularly imprinted polymer. J Hazard Mater 187:274-82 CrossRef
  29. Hu Y, Li Y, Zhang Y, Li G, Chen Y (2011) Development of sample preparation method for auxin analysis in plants by vacuum microwave-assisted extraction combined with molecularly imprinted clean-up procedure. Anal Bioanal Chem 399:3367-374 CrossRef
  30. Zhang Y, Liu R, Hu Y, Li G (2009) Microwave heating in preparation of magnetic molecularly imprinted polymer beads for trace triazines analysis in complicated samples. Anal Chem 81:967-76 CrossRef
  31. Xu S, Jiang C, Lin Y, Jia L (2012) Magnetic nanoparticles modified with polydimethylsiloxane and multi-walled carbon nanotubes for solid-phase extraction of fluoroquinolones. Microchim Acta 179:257-64 CrossRef
  32. He Z, Liu D, Li R, Zhou Z, Wang P (2012) Magnetic solid-phase extraction of sulfonylurea herbicides in environmental water samples by Fe₃O₄@dioctadecyl dimethyl ammonium chloride@silica magnetic particles. Anal Chim Acta 747:29-5 CrossRef
  33. Yang C, Wang G, Lu Z, Sun J, Zhuang J, Yang W (2005) Effect of ultrasonic treatment on dispersibility of Fe₃O₄ nanoparticles and synthesis of multi-core Fe₃O₄/SiO₂ core/shell nanoparticles. J Mater Chem 15:4252-257 CrossRef
  34. Qu P, Lei J, Zhang L, Ouyang R, Ju H (2010) Molecularly imprinted magnetic nanoparticles as tunable stationary phase located in microfluidic channel for enantioseparation. J Chromatogr A 1217:6115-121 CrossRef
  35. Council Directive 98/83/EC of 3 November 1998 on the quality of water intended for human consumption. Official Journal of the European Communities, L 330/32
  
• 作者单位：María Jesús Lerma-García (1) (2)
  Mohammed Zougagh (2) (3)
  Angel Ríos (1) (2)
  
  1. Department of Analytical Chemistry and Food Technology, University of Castilla–La Mancha, Av. Camilo José Cela 10, 13004, Ciudad Real, Spain
  2. Regional Institute for Applied Chemistry Research, IRICA, Av. Camilo José Cela 10, 13004, Ciudad Real, Spain
  3. Albacete Science and Technology Park, 02006, Albacete, Spain
  
• ISSN：1436-5073

文摘

We have developed a simple method for the extraction of sulfonylurea herbicides (SUHs) from environmental water samples. It is based on a magnetic molecular imprint (MMIP) as a sorbent. The MMIP was prepared using metsulfuron-methyl as the template molecule, methacrylic acid as the functional monomer, trimethylolpropane trimethacrylate as the cross-linking agent, and magnetite as the magnetic component. Extraction can be carried out by blending and stirring water sample, extraction solvent and MMIP. Once the extraction is completed, the MMIP containing the SUHs can be separated from the sample matrix with a magnet. The SUHs desorbed from the polymers were then quantified by capillary liquid chromatography with diode array detection. The limits of quantification are in the range of 0.08 to 0.1?ng?mL?. Repeatabilities of peak areas and retention times range from 2.9?% to 4.0?% and from 0.1?% to 0.3?%, respectively. The method was successfully applied to the determination of the SUHs bensulfuron-methyl, metsulfuronmethyl, pyrazosulfuron-methyl, thifensulfuron-methyl, and triasulfuron in waste water samples. Recoveries range from 94.3?% to 102.3?%. Figure Scheme of sulfonylurea herbicide preconcentration