Removal of heavy metal chromium from tannery effluent using ultrafiltration membrane

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• 作者：P. Angelin Vinodhini ; P. N. Sudha
• 关键词：Cellulose acetate ; Nanochitosan ; Polyethylene glycol ; Ultrafiltration membrane ; Remediation of tannery effluent
• 刊名：Textiles and Clothing Sustainability
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：2
• 期：1
• 全文大小：2,254 KB
• 刊物类别：Textile Engineering; Environmental Management; Sustainable Development; Industrial Chemistry/Chemica
• 刊物主题：Textile Engineering; Environmental Management; Sustainable Development; Industrial Chemistry/Chemical Engineering; Characterization and Evaluation of Materials; Engineering Economics, Organization, Lo
• 出版者：Springer Singapore
• ISSN：2197-9936

文摘

The present study was aimed to fabricate a novel ultrafiltration membrane using cellulose acetate, nanochitosan, and polyethylene glycol of ratio 1:2:2 by phase inversion method. Analytical techniques such as Fourier transform infrared spectroscopy (FTIR), X-ray diffractometer (XRD), and scanning electron microscopy (SEM) have been employed to characterize the prepared membrane. FTIR and XRD results revealed the formation of blended membrane with increased amorphous nature. SEM studies exhibited the rough surface with numerous pores. The prepared membrane was also characterized for its ultrafiltration performance by membrane compaction, pure water flux, water content, and porosity. The results showed that the membrane obtained a pure water flux of 25.32 l/m2 h. The water content was found to be 24 % and a high porosity of 83 % was obtained which showed the membrane’s high hydrophilicity and more porous nature. The main focus of the present study was toxic hexavalent chromium removal from tannery effluent using the prepared hydrophilic membrane, which causes various adverse effects. The effect of pH of the solution (viz., pH 5, 7, and 9), membrane thickness (0.1 and 0.2 mm), and the applied pressure (50 and 100 kPa) were studied which are the key factors in determining the efficiency of the prepared membrane in remediation of tannery effluent. The results showed high percentage removal of chromium at pH 7 using 0.2 mm thickness at 100 kPa. The physicochemical parameters of the tannery effluent were also found to be reduced.