Catalytic activity of SBA-15-grafted indium tri-isopropoxide in chemoselective MPV reductions

详细信息    查看全文

• 作者：Burcu Uysal ; Birsen S. Oksal
• 关键词：Mesoporous SBA ; 15 ; Indium tri ; isopropoxide ; Chemoselectivity ; α ; β ; Unsaturated aldehydes and ketones ; MPV reduction
• 刊名：Journal of Porous Materials
• 出版年：2015
• 出版时间：August 2015
• 年：2015
• 卷：22
• 期：4
• 页码：1053-1064
• 全文大小：1,534 KB
• 参考文献：1.G. Brieger, T.J. Nestrick, Chem. Rev. 74, 567-80 (1974)View Article
  2.E.J. Creyghton, R.S. Downing, J. Mol. Catal. A Chem. 134, 47-1 (1998)View Article
  3.E.J. Creyghton, J. Huskens, J.C. van der Waal, H. van Bekkum, in Heterogeneous Catalysis and Fine Chemicals IV, ed. by H.U. Blaser, A. Baiker, R. Prins (Elsevier, Amsterdam, 1997)
  4.J.E. Bailey, M. Bohnet, J. Brinker, Ullmann’s Encyclopedia of Technical Chemistry, 6th edn. (Wiley-VCH, London, 2000)
  5.E.J. Creyghton, S.D. Ganeshie, R.S. Downing, H. van Bekkum, J. Mol. Catal. A 115, 457-72 (1997)View Article
  6.P.J. Kunkeler, B.J. Zuurdeeg, J.C. van der Waal, J.A. van Bokhoven, D.C. Koningsberger, H. van Bekkum, J. Catal. 180, 234 (1998)View Article
  7.A. Corma, M.E. Domine, S. Valencia, J. Catal. 215, 294 (2003)View Article
  8.R. Anwander, C. Palm, Stud. Surface Sci. 117, 413 (1999)
  9. R. Anwander, C. Palm, G. Gerstberger, O. Groeger, G. Engelhardt, Chem. Commun. 1811-812 (1998)
  10.V.A. Ivanov, J. Bachelier, F. Audry, J.C. Lavalley, J. Mol. Catal. 91, 45 (1994)View Article
  11.P. Leyrit, C. Mc Gill, F. Quignard, A. Choplin, J. Mol. Catal. A Chem. 112, 395-00 (1996)View Article
  12.J.C. Van der Waal, E.J. Creyghton, P.J. Kunkeler, K. Tan, H. Van Bekkum, Top. Catal. 4, 261-68 (1997)View Article
  13.C.T. Kresge, M.E. Leonowicz, W.J. Roth, J.C. Vartuli, J.S. Beck, Nature 359, 710-12 (1992)View Article
  14.J.Y. Ying, C.P. Mehnert, M.S. Wong, Angew. Chem. Int. Ed. 38, 56-7 (1999)View Article
  15.F. Schüth, Chem. Mater. 13, 3184-195 (2001)View Article
  16.Y. Wan, D.Y. Zhao, Chem. Rev. 107, 2821-860 (2007)View Article
  17.Y. Han, D. Zhang, Curr. Opin. Chem. Eng. 1, 129-37 (2012)View Article
  18.W.J.J. Stevens, K. Lebeau, M. Mertens, G. van Tendeloo, P. Cool, E.F. Vansant, J. Phys. Chem. B 110, 9183-187 (2006)View Article
  19.A. Taguchi, F. Schüth, Microporous Mesoporous Mater. 77, 1-5 (2005)View Article
  20.A. Corma, Chem. Rev. 97, 2373-419 (1997)View Article
  21.F. Zhang, Y. Yan, H. Yang, Y. Meng, C. Yu, B. Tu, D. Zhao, J. Phys. Chem. 109, 8723-732 (2005)View Article
  22.N. Rahmat, A.A. Zuhairi, A. Rahman Mohamed, Am. J. Appl. Sci. 7, 1579-586 (2010)View Article
  23.W. M. Haynes. in: CRC Handbook of Chemistry and Physics: A Ready-Reference Book of Chemical and Physical Data, ed. by David R. Lide (CRC Press, Boca Raton, 2010). ISBN 978-1-4398-2077-3
  24.A.F. Holleman, E. Wiberg, N. Wiberg. “Thallium- Lehrbuch der Anorganischen Chemie (in German) (91-00 ed.). (Walter de Gruyter, 1985), pp. 892-93. ISBN 3-11-007511-3
  25.D. Zhao, J. Feng, Q. Huo, N. Melosh, G.H. Fredrickson, B.F. Chmelka, G.D. Stucky, Science 279, 548-52 (1998)View Article
  26.D. Zhao, Q. Huo, J. Feng, B.F. Chmelka, G.D. Stucky, J. Am. Chem. Soc. 120, 6024-036 (1998)View Article
  27.D. Zhao, J. Sun, Q. Li, G.D. Stucky, Chem. Mater. 12, 275-79 (2000)View Article
  28.D. Zhao, Q. Huo, J. Feng, B.F. Chmelka, G.D. Stucky, Am. Chem. Soc. 120, 6024-036 (1998)View Article
  29.J.S. Lettow, Y.J. Han, P. Schmidt-Winkel, P.D. Yang, D.Y. Zhao, G.D. Stucky, J.Y. Ying, Langmuir 16, 8291-295 (2000)View Article
  30.M. Misono, N. Noijri, Appl. Catal. 64, 1 (1990)View Article
  31.F.J. Urbano, M.A. Aramendía, A. Marinas, J.M. Marinas, J. Catal. 268, 79-8 (2009)View Article
  32.J.M. Hidalgo, C.J. Sanchidrián, J.R. Ruiz, Appl. Catal. A 470, 311-17 (2014)View Article
  33.J.P. Thielemann, F. Girgsdies, R. Schl?gl, C. Hess, Beilstein J. Nanotechnol. 2, 110-18 (2011)View Article
  34.H. Darmstadt, C. Roy, S. Kaliaguine, S.H. Joo, R. Ryoo, Microporous Mesoporous Mater. 60, 139-49 (2003)View Article
  35.M. Kruk, M. Jaroniec, C.H. Ko, R. Ryoo, Chem. Mater. 12, 1961-968 (2000)View Article
  36.A. Sterczynska, A.D. Marczewska, M.S. Bartkowiak, J.Z. Piotrowska, M. Jarek, K. Domin, J. Therm. Anal. Calorim. 118, 263-76 (2014)View Article
  37.J.L. Namy, J. Souppe, J.H.B. Collin Kagan, J. Org. Chem. 49, 2045-049 (1984)View Article
  38.B. Uysal, B.S. Buyuktas, Ark?voc 14, 134-40 (2007)View Article
  39.B. Uysal, B.S. Oksal, J. Chem. Sci. 123, 681-85 (2011)View Article
  40.J. Lee, T. Ryu, S. Park, P.H. Lee, J. Org. Chem. 77, 4821-825 (2012)View Article
  41.B. Uysal, B.S. Oksal, Appl. Catal. A Gen. 435, 204-16 (2012)View Article
  42.S. Shylesh, M.P. Kapoor, L.R. Juneja, P.P. Samuel, C. Srilakshmi, A.P. Singh, J. Mol. Catal. A Chem. 301, 118-26 (2009)View Article
  43.S. Narayanan, Bull. Catal. Soc. Ind. 2, 107-21 (2003)
  44.W. Bonrath, T. Netscher, Appl. Catal. A 280, 55-3 (2005)View Article
  45.A. Corma, S. Iborra, A. Velty, Chem. Rev. 107, 2411-502 (2007)View Article
  46.A. Stolle, T. Gallert, C. Schm?ger, B. Ondruschka, RSC Adv. 3, 2112-153 (2013)View Article
  47.Y. Zhu, S. Liu, S. Jaenicke, G. Chuah, Catal. Today 97, 249-55 (2004)View Article
  48.S. Carnesecchi, Y. Schneider, J. Ceraline, B. Duranton, F. Gosse, N. Seiler, F. Raul, J. Pharmacol. Exp. Ther. 298
• 作者单位：Burcu Uysal (1)
  Birsen S. Oksal (2)
  
  1. Technical Sciences Vocational High School, Pamukkale University, Denizli, Turkey
  2. Department of Chemistry, Art and Science Faculty, Giresun University, Giresun, Turkey
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Characterization and Evaluation Materials
  Physical Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1573-4854

文摘

Indium tri-isopropoxide-containing heterogeneous In(O i Pr)3–SBA-15 catalyst were synthesized by grafting method and were then used as catalyst in the Meerwein–Ponndorf–Verley (MPV) reduction of various carbonyl compounds using 2-propanol as the hydrogen transfer agent. The prepared new heterogeneous catalyst, In(O i Pr)3–SBA-15, was characterized in details by using XRD, 29Si NMR,13C NMR, TEM, N2 adsorption and ICP-OES. New heterogeneous catalyst has been studied in the chemoselective MPV reduction of unsaturated aldehydes and ketones. Good activity and selectivity to the reduced unsaturated alcohols, citronellol, cinnamalcohol, α-ionol, 3-methyl-2-butanol, geraniol, nerol were observed over indium tri-isopropoxide supported on silica. The In(O i Pr)3–SBA-15 catalyst is recyclable up to six cycles without any significant loss in its catalytic activity. Eventually, In(O i Pr)3–SBA-15 has been found that active catalyst in the MPV reactions of carbonyl compounds including unsaturated aldehydes and ketones with excellent conversion, selectivity and reusability.