Synthesis, luminescent sensing based on a three-fold interpenetrating network with flexible carboxylates

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• 作者：S. L. Cai ; T. Wang ; J. Wang ; B. Xie ; Y. Wu
• 关键词：structure ; topology ; luminescent sensing
• 刊名：Russian Journal of Coordination Chemistry
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：43
• 期：1
• 页码：50-54
• 全文大小：
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Physical Chemistry; Inorganic Chemistry;
• 出版者：Pleiades Publishing
• ISSN：1608-3318
• 卷排序：43

文摘

A Zn-based complexes with chemical formulae {[Zn(L)_0.5(4,4'-Bipy)] · 2H₂O} (I) (H₄L = 5,5'-(1,4-phenylene-bis(methylene))bis(oxy) diisophthalic acid), has been synthesized and structurally characterized. Single-crystal X-ray crystallography (CIF file CCDC no. 1465538) reveals that compound I shows a three-dimensional three-fold interpenetrating network simplified by a bbf topology (vertex symbol (66)₂(64.82)). Complex I can work as highly sensitive sensors to Cu2+, CrO₄2- and explosive by luminescent quenching.