One-pot facile co-precipitation synthesis of the layered Li1 + x (Mn0.6Ni0.2Co0.2)
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- 作者：Shaomeng Ma ; Xianhua Hou ; Zanrui Lin…
- 关键词：Lithium ; ion batteries ; Li ; rich cathode ; Co ; precipitation ; Li1 + x (Mn0.6Ni0.2Co0.2)1 − lic ">x O2
- 刊名：Journal of Solid State Electrochemistry
- 出版年：2016
- 出版时间：January 2016
- 年：2016
- 卷：20
- 期：1
- 页码：95-103
- 全文大小：2,488 KB
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Xianhua Hou (1) (2)
Zanrui Lin (1)
Yanling Huang (1)
Yumei Gao (3)
Shejun Hu (1) (2)
Jiadong Shen (1)
1. Guangdong Provincial Key Laboratory of Quantum Engineering and Quantum Materials, School of Physics and Telecommunication Engineering, South China Normal University, Guangzhou, 510006, China
2. Engineering Research Center of Materials and Technology for Electrochemical Energy Storage (Ministry of Education), Guangzhou, 510006, China
3. Zhongshan Institute, University of Electronic Science and Technology, Zhongshan, 528400, China - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Physical Chemistry
Analytical Chemistry
Industrial Chemistry and Chemical Engineering
Characterization and Evaluation Materials
Condensed Matter
Electronic and Computer Engineering - 出版者：Springer Berlin / Heidelberg
- ISSN：1433-0768
文摘
The Li-rich layered Li1 + x (Mn0.6Ni0.2Co0.2)1 − lic ">x O2 (x = 0.14, 0.165, 0.19) cathode materials have been successfully synthesized through a one-pot facile co-precipitation route. The synthesized MCO3 (M = Mn0.6Ni0.2Co0.2) precursor mixing with Li2CO3 was annealed at 500 °C and calcinated at 900 °C. The morphology and structure of the samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The results indicate that the sample Li1.165Mn0.501Ni0.167Co0.167O2 (x = 0.165) exhibits the most outstanding electrochemical performance, which may be ascribed to uniform particle size and high crystallinity. It delivers an initial discharge-specific capacity of approximately 241.7 mAh g−1 with an initial coulombic efficiency of 70.3 % at a constant density of 25 mA g−1. A reversible discharge-specific capacity of approximately 207.2 mAh g−1 is still obtained after 100 cycles. The discharge capacities of nearly 226.8, 194.4, 158.9, 143.7, 116.8, 97.5, and 47.6 mAh g−1 can also be attained under 0.1 C, 0.2 C, 0.5 C, 1 C, 2 C, 5 C, and 10 C (1 C = 250 mA g−1), respectively. The Li-rich layered Li1.165Mn0.501Ni0.167Co0.167O2 will be a promising cathode material for advanced lithium-ion batteries.