Hydroformylation of 1-octene over nanotubular TiO2-supported amorphous Co-B catalysts

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• 作者：Yukun Shi ; Xiaojing Hu ; Baolin Zhu…
• 关键词：Hydroformylation ; TiO2 nanotubes ; Amorphous Co ; B ; 1 ; Octene
• 刊名：Chemical Research in Chinese Universities
• 出版年：2015
• 出版时间：October 2015
• 年：2015
• 卷：31
• 期：5
• 页码：851-857
• 全文大小：673 KB
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• 作者单位：Yukun Shi (1)
  Xiaojing Hu (1)
  Baolin Zhu (1)
  Shoumin Zhang (1)
  Weiping Huang (1)
  
  1. Department of Chemistry, Collaborative Innovation Center of Chemical Science and Engineering, The Key Laboratory of Advanced Energy Materials Chemistry, Ministry of Education, Tianjin Key Lab of Metal and Molecule-based Material Chemistry, Nankai University, Tianjin, 300071, P. R. China
  
• 刊物主题：Chemistry/Food Science, general; Analytical Chemistry; Inorganic Chemistry; Organic Chemistry; Physical Chemistry;
• 出版者：Springer Berlin Heidelberg
• ISSN：2210-3171

文摘

TiO<sub>2sub> nanotubes supported amorphous Co-B(Co-B/TNTs) catalyst was prepared via impregnationchemical reduction procedure. The catalyst was characterized with transmission electron microscopy(TEM), ammonia temperature-programmed desorption(NH<sub>3sub>-TPD), thermogravimetry-differential thermal analysis(TG-DTA), Fourier transform infrared spectroscopy(FTIR) and Raman spectroscopy. The effects of temperature and ratio of CO to H<sub>2sub> on the hydroformylation of 1-octene were studied. At an optimized reaction temperature(150 °C) and volume ratio of CO to H<sub>2sub>(2:1), the conversion of 1-octene can reach 97.4% with a selectivity of 23.1% for total aldehydes and n/i-aldehyde molar ratio of 40:60. To obtain higher selectivity for linear aldehydes, Co-B/TNTs modified with triphenylphosphine for the hydroformylation of 1-octene were investigated. When molar ratio of P/Co was 4, the yield of total aldehydes was the highest(31.6%) with a good selectivity for linear product(n/i-aldehyde molar ratio was 70:30). In recycle use, the Co-B/TNTs catalyst modified with triphenylphosphine could be reused five times without reducing the activity and selectivity obviously. For a comparative study, all the Co-B/TNTs to catalyze the hydroformylation of other olefins exhibited high conversion under the optimized conditions. Keywords Hydroformylation TiO<sub>2sub> nanotubes Amorphous Co-B 1-Octene