Novel β-cyclodextrin-[60]fullerene conjugates based on Huisgen [2+3] cycloaddition: synthesis and dyes complexation properties

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• 作者：Hongyu Guo ; Xiaoting Fang ; Fafu Yang…
• 关键词：β ; Cyclodextrin ; [60]fullerene ; Synthesis ; Complexation ; Dye
• 刊名：Journal of Inclusion Phenomena and Macrocyclic Chemistry
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：84
• 期：1-2
• 页码：79-86
• 全文大小：668 KB
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• 作者单位：Hongyu Guo (1)
  Xiaoting Fang (1)
  Fafu Yang (1) (2)
  Yingmei Zhang (1)
  
  1. College of Chemistry and Chemical Engineering, Fujian Normal University, Fuzhou, 350007, People’s Republic of China
  2. Fujian Key Laboratory of Polymer Materials, Fuzhou, 350007, People’s Republic of China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Organic Chemistry
  Food Science
  Crystallography
  
• 出版者：Springer Netherlands
• ISSN：1573-1111

文摘

By using β-cyclodextrin aromatic aldehyde derivatives 5 and 6 as starting materials, the novel β-cyclodextrin-[60]fullerene conjugate 7 and bis-β-cyclodextrin-[60]fullerene conjugate 8 were designed and conveniently synthesized via the Huisgen [2+3] cycloaddition for the first time. The UV–Vis complexation experiments, fluorescence titration spectra and complexation ESI–MS spectrum suggested that they possessed excellent binding abilities for dyes with 1:1 host–guest complexes. The highest association constant of compound 8 for Orange I was as high as 6.97 × 105. Keywords β-Cyclodextrin [60]fullerene Synthesis Complexation Dye