Assessing spatial distribution, sources, and human health risk of organochlorine pesticide residues in the soils of arid and semiarid areas of northwest China

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• 作者：Tao Huang (1)
  Qiang Guo (1)
  Hui Tian (1)
  Xiaoxuan Mao (1)
  Zhongyuan Ding (1)
  Gan Zhang (2)
  Jun Li (2)
  Jianmin Ma (1)
  Hong Gao (1)
  
• 关键词：Organochlorine pesticides (OCPs) ; Soil ; Spatial distribution ; Sources ; Health risk assessment
• 刊名：Environmental Science and Pollution Research
• 出版年：2014
• 出版时间：May 2014
• 年：2014
• 卷：21
• 期：9
• 页码：6124-6135
• 全文大小：
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• 作者单位：Tao Huang (1)
  Qiang Guo (1)
  Hui Tian (1)
  Xiaoxuan Mao (1)
  Zhongyuan Ding (1)
  Gan Zhang (2)
  Jun Li (2)
  Jianmin Ma (1)
  Hong Gao (1)
  
  1. Key Laboratory of Western China’s Environmental Systems (Ministry of Education), College of Earth and Environmental Sciences, Lanzhou University, Lanzhou, 730000, People’s Republic of China
  2. State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, 510640, China
  
• ISSN：1614-7499

文摘

Thirty-two topsoil samples were collected to analyze the residue levels of organochlorine pesticides (OCPs) in topsoil of arid and semiarid areas of northwest China in 2011. Results showed that DDTs were the dominant contaminants with a mean concentration of 12.52?ng/g. The spatial distribution characteristics indicated that α-hexachlorocyclohexanes (HCHs) were mainly used in rural sites, whereas hexachlorobenzene (HCB) and endosulfan were detected mostly in urban areas. DDTs, heptachlor, and chlordane were found almost equally in both urban and rural areas. Source identification revealed that the current levels of HCHs in soils were attributable to the residues from their historical use and fresh usage of lindane (γ-HCH). DDTs were mainly from historical use and fresh usage of dicofol, and HCB was emitted from the chemical industry. It was also found that the current soil levels of heptachlor were mainly from its historical usage, endosulfan from fresh input, and chlordane from long-range atmospheric transport, respectively. The noncarcinogenic health risk assessment with a model was also conducted using USEPA standards for adults and children. Results indicated that health risk under nondietary exposure to OCPs decreased in the sequence of ΣDDT-gt;?ΣHCH-gt;?HCB-gt;?Σheptachlor-gt;?Σendosulfan-gt;?Σchlordane. According to the reference dose from the USEPA, the health risk under nondietary exposure to OCPs in the soil samples was at a relatively safe level.