Investigation of Ce0.9Sr0.1Cr0.5Co0.5O3?ο/sub> as the anode material for solid oxide fuel cells fueled
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- 作者：Xiufang Zhu (1)
Yingying Shi (1)
Aiping Li (1)
Qin Zhong (2) - 关键词：Solid oxide fuel cell ; Anode catalyst ; Electrical conductivity ; H2S
- 刊名：Ionics
- 出版年：2014
- 出版时间：July 2014
- 年：2014
- 卷：20
- 期：7
- 页码：1011-1021
- 全文大小：
- 参考文献：1. Vorontsov V, Luo JL, Sanger AR, Chuang KT (2008) Synthesis and characterization of new ternary transition metal sulfide anodes for H2S-powered solid oxide fuel cell. J Power Sources 183:76-3 CrossRef
2. Ober J (2004) US geological survey minerals yearbook. Sulfur US Geol Surv 74:1-8
3. Beavon DK, Kouzel B, Ward JW (1981) Claus processing of novel acid gas streams. Div EletroChem Am Chem Soc 26:237-45
4. Song LJ, Du GW, Di Y (1999) Modification of larch bark Tannin extract by intensive sulfitation. Chem Ind For Prod 19:1-
5. Pujare NU, Semkow KW, Sammells AF (1987) A direct H2S/air solid oxide fuel cell. J Electrochem Soc 134:2639-640 CrossRef
6. Sammells AF, Patel J, Osborne J, Cook RL (1992) Intermediate temperature electrochemical Claus process for sulfur recovery. Gas Sep Purif 6:141-47 CrossRef
7. Kirk TJ, Winnick J (1993) A hydrogen sulfide solid oxide fuel using ceria-based electrolyte. J Electrochem Soc 140:3494-496 CrossRef
8. Ong BG, Lin TA, Mason DM (1987) Proc Electrochem Soc Ser 12:295-06
9. Weaver D, Winnick J (1987) Electrochemical removal of H2S from hot gas streams. J Electrochem Soc 134:2451-458 CrossRef
10. Xu Z, Luo J, Chuang KT (2007) CoS-promoted MoS2 catalysts for SOFC using H2S-containing hydrogen or syngas as fuel. J Electrochem Soc 154:B523–B527 CrossRef
11. Galea NM, Kadantsev ES, Ziegler T (2009) Modeling hydrogen sulfide adsorption on Mo-edge MoS2 surfaces under solid oxide fuel cell conditions. J Phys Chem C 113:193-03 CrossRef
12. Peterson D, Winnick J (1998) Utilization of hydrogen sulfide in an intermediate-temperature ceria-based solid oxide fuel cell. J Electrochem Soc 145:1449-453 CrossRef
13. Liu M, He P, Wei G, Luo J, Sanger AR, Chuang KT (2001) Performance of a solid oxide fuel cell utilizing hydrogen sulfide as fuel. J Power Sources 94:20-5 CrossRef
14. Yates C, Winnick J (1999) Anode materials for a hydrogen sulfide solid oxide fuel cell. J Electrochem Soc 146:2841-844 CrossRef
15. Miao MS, Qu HX, Zhong Q, Tan WY (2008) Preparation and performance of H2S solid oxide fuel cell. New Chem Mater 36:70-5 (in Chinese)
16. Feng F, Qu HX, Tan WY, Zhong Q (2008) Desulphurization characteristic of H2S/air solid oxide fuel cell. Chin J Appl Chem 25:199-03 (in Chinese)
17. Aguilar L, Zha S, Cheng Z, Winnick J, Liu M (2004) A solid oxide fuel cell operating on hydrogen sulfide (H2S) and sulfur-containing fuels. J Power Sources 135:17-4 CrossRef
18. Aguilar L, Zha S, LI S, Winnick J, Liu M (2004) Sulfur-tolerant materials for the hydrogen sulfide SOFC. Electrochem Solid-State Lett 7:A324–A326 CrossRef
19. Cheng Z, Zha S, Aguilar L, Wang D, Winnick J, Liu M (2006) A solid oxide fuel cell running on H2S/CH4 fuel mixtures. Mix Electrochem Solid-State Lett 9:A31–A33 CrossRef
20. Hui S, Petric A (2001) Conductivity and stability of SrVO3 and mixed perovskites at low oxygen partial pressures. Solid State Ionics 143:275-83 CrossRef
21. Cheng Z, Zha S, Aguilar L, Liu M (2005) Chemical, electrical, and thermal properties of strontium doped lanthanum vanadate. Solid State Ionics 176:1921-928 CrossRef
22. Yokio Y, Uchida H (1998) Catalytic activity of perovskite-type oxide catalysts for direct decomposition of NO: correlation between cluster model calculations and temperature-programmed desorption experiments. Catal Today 42:167-74 CrossRef
23. Zhu X, Zhong Q, Xu D et al (2013) Further investigation of Ce0.9Sr0.1Cr0.5Fe0.5O4±δ as anode for solid oxide fuel cell fuelled with H2S. J Alloys Compd 555:169-75 CrossRef
24. Gong M, Liu X, Trembly J et al (2007) Sulfur-tolerant anode materials for solid oxide fuel cell application. J Power Sources 168:289-98 CrossRef
25. Danilovic N, Luo JL, Chuang KT, Sanger AR (2009) Effect of substitution with Cr3+ and addition of Ni on the physical and electrochemical properties of Ce0.9Sr0.1VO3 as a H2S-active anode for solid oxide fuel cells. J Power Sources 194:252-62 CrossRef
26. Danilovic N, Luo JL, Chuang KT, Sanger AR (2009) Ce0.9Sr0.1VOx ( / x--, 4) as anode materials for H2S-containing CH4 fueled solid oxide fuel cells. J Power Sources 192:247-57 CrossRef
27. C. Reiichi, Y. Bunichi, S. Yoji, T. Yoshitaka, A. Masayasu, Japanese patent, JP2004186148A
28. Wu WC, Huang JT, Chiba A (2010) Synthesis and properties of Samaria-doped ceria electrolyte for IT-SOFCs by EDTA-citrate complexing method. J Power Sources 195:5868-874 CrossRef
29. Zhu XF, Zhong Q, Zhao XJ, Yan H (2011) Synthesis and performance of Y-doped La0.7Sr0.3CrO3-δ as potential anode material for solid oxygen fuel cells. Appl Surf Sci 257:1967-971 CrossRef
30. Kittel C (2005) Introduction to solid state physics, 8th edn. Wiley, Berkley
31. Weber WJ, Griffin CW, Bates L (1987) Effects of cation substitution on electrical and thermal transport properties of YCrO3 and LaCrO3. J Am Ceram Soc 70(4):265-70 CrossRef
32. Feifei D, Yubo C, Ran R et al (2013) BaNb0.05Fe0.95O3-δ as a new oxygen reduction electrocatalyst for intermediate temperature solid oxide fuel cells. J Mater Chem A 1:9781-791 CrossRef
33. Dong F, Chen D, Chen Y et al (2012) La-doped BaFeO3-δ perovskite as a cobalt-free oxygen reduction electrode for solid oxide fuel cells with oxygen-ion conducting electrolyte. J Mater Chem 22:15701-5709
34. Yunfei B (2013) Redox stability and sulfur resistance of Sm0.9Sr0.1CrxFe1-xO3-δ perovskite materials. J Alloys Compd 578:60-6 CrossRef
35. Dai H, Hong H, Li P et al (2004) The relationship of structural defect–redox property–catalytic performance of perovskites and their related compounds for CO and NOx removal. Catal Today 90:231-44 CrossRef
36. Zhang K, Ge L, Ran R et al (2008) Synthesis, characterization and evaluation of cation-ordered LnBaCo2O5+δ as materials of oxygen permeation membranes and cathodes of SOFCs. Acta Mater 56:4876-889 CrossRef
37. Park J, Zou J, Yoon H et al (2011) Electrochemical behavior of Ba0.5Sr0.5Co0.2-xZnxFe0.8O3-δ ( / x---.2) perovskite oxides for the cathode of solid oxide fuel cells. Int J Hydrog Energy 36:6184-193 CrossRef
38. Yang H, Lu WQ (2001) Application of electrochemical. Science, Beijing, pp 55-0
39. Hao H, Liu R (2009) Preparation and properties of cobalt-doped ceria (CDC) for IT-SOFCs anodes in natural gas. J Inorg Mater 24(3):539-44 CrossRef
40. Mao ZQ (2005) Fuel cell. Chemical industry press, Beijing
41. Wu ZB, Jin RB, Liu Y, Wang HQ (2008) Ceria modified MnOx/TiO2 as a superior catalyst for NO reduction with NH3 at low-temperature. Catal Commun 9:2217-220 CrossRef
42. Romeo M, Bak K, Fallah JE, Normand FL, Hilaire L (1993) XPS study of the reduction of cerium dioxide. Surf Interface Anal 20:508-12 CrossRef
43. W. Tan, H. Yan, D. Xu, et al. (2013) Electrochemical behaviors of Y-doped La0.7Sr0.3CrO3-δ anode in sulfur-containing fuel SOFC. Int J Hyd En 250:143-51
44. Xu D, Zhu X, Bu Y, Yan H, Tan W, Zhong Q (2012) Synthesis and performance of Sm0.9Sr0.1Cr0.5Fe0.5O3±δ as anode material for SOFCs running on H2S-containing fuel. Ionics 19(3):491-97
45. Kang M, Park ED, Kim JM, Yie JE (2007) Manganese oxide catalysts for NOx reduction with NH3 at low temperatures. Appl Catal A 327:261-69 CrossRef
46. Yu D, Liu Y, Wu ZB (2011) Screening study of transition metal oxide catalysts supported on ceria-modified titania for catalytic oxidation of toluene. J Zhejiang Univ-Sci A (Appl Phys & Eng) 12(6):461-69 CrossRef
47. Dupin JC, Gonbeau D, Vinatier P et al (2000) Systematic XPS studies of metal oxides, hydroxides and peroxides. Phys Chem Chem Phys 2:1319-324 CrossRef
48. Eom Y, Jeon SH, Ngo TA et al (2008) Heterogeneous mercury reaction on a selective catalytic reduction (SCR) catalyst. Catal Lett 121:219-25 CrossRef - 作者单位：Xiufang Zhu (1)
Yingying Shi (1)
Aiping Li (1)
Qin Zhong (2)
1. School of Life Science and Chemical Engineering, Huaiyin Institute of Technology, Meicheng Road, Huaian, 223003, Jiangsu, People’s Republic of China
2. School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210094, People’s Republic of China - ISSN：1862-0760
文摘
Ce0.9Sr0.1Cr0.5Co0.5O3?ο/sub> (CSCrCo) as an anode catalyst was studied in a solid oxide fuel cell (SOFC), where hydrogen sulfide (H2S) was used as fuel. The conductivities were evaluated with a four-probe DC technique in 3?% H2-N2 and 5?% H2S-N2 at 570-00?°C, respectively. X-ray diffraction (XRD) patterns show that CSCrCo powders are fluorite structure which is similar to that of CeO2 parent (JCPDS card no. 34-0394). Meanwhile, CSCrCo anode material has good chemical compatibility with electrolyte (Ce0.8Sm0.2O1.9 (SDC)) in N2. Through the analysis of XRD and Fourier transform infrared patterns, no other new phase is detected after treatment in 5?% H2S-N2 at 800?°C for 5?h, which indicate that the material has a good sulfur tolerance. H2 temperature-programmed reduction and Tafel curves indicate that the temperature of the best catalytic activity is 600?°C. The electrochemical properties of the cell comprising CSCrCo-SDC/SDC/Ag are measured in 5?% H2S-N2 at low temperatures (500 and 600?°C). The maximal open circuit voltage is 1.04?V, the maximal power density is 12.55?mW?cm?, and the maximal current density is 40?mA?cm? at 500?°C. While at 600?°C, the corresponding values are 0.95?V, 14.21?mW?cm?, and 90.01?mA?cm?, respectively. After SOFC operating in 5?% H2S, X-ray photoelectron spectroscopy is used to compare the fresh sample with the H2S-treated one.