Preconcentration of the antibiotic enrofloxacin using a hollow molecularly imprinted polymer, and its quantitation by HPLC

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• 作者：Yiwei Tang ; Min Li ; Xue Gao ; Xiuying Liu ; Yong Ma ; Yi Li ; Yongxia Xu…
• 关键词：Solid ; phase extraction ; Potassium tetratitanate ; Polymethacrylate ; X ; ray powder diffraction ; Transmission electron microscopy ; Food analysis
• 刊名：Microchimica Acta
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：183
• 期：2
• 页码：589-596
• 全文大小：774 KB
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• 作者单位：Yiwei Tang (1) (2) (3)
  Min Li (1) (2)
  Xue Gao (2) (3)
  Xiuying Liu (1) (3)
  Yong Ma (2) (3)
  Yi Li (1)
  Yongxia Xu (1)
  Jianrong Li (1) (2) (3)
  
  1. College of Food Science and Project Engineering, Bohai University, Jinzhou, 121013, China
  2. Food Safety Key Lab of Liaoning Province, Bohai University, Jinzhou, 121013, China
  3. National & Local Joint Engineering Research Center of Storage, Processing and Safety Control Technology for Fresh Agricultural and Aquatic Products, Bohai University, Jinzhou, 121013, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Analytical Chemistry
  Inorganic Chemistry
  Physical Chemistry
  Characterization and Evaluation Materials
  Monitoring, Environmental Analysis and Environmental Ecotoxicology
  
• 出版者：Springer Wien
• ISSN：1436-5073

文摘

Hollow molecularly imprinted polymers (h-MIPs) consisting of K₂Ti₄O₉ as a sacrifice matrix were synthesized for selective recognition of enrofloxacin (ENR). The h-MIPs possess a characteristic nanostructure and were characterized by Fourier transform infrared spectroscopy, X-ray powder diffraction and transmission electron microscopy. The h-MIPs have a fast adsorption kinetic (~10 min), high adsorption capacity and a good selectivity factor (2.4) for ENR. Following adsorption of ENR, it was eluted from the sorbent with methanol-acetic acid (8:2) and quantified by HPLC. The calibration plot extends from 0.5 to 16.0 ng mL‾^{1 of ENR with a correlation coefficient of 0.9912, and the limit of detection is 0.24 ng mL‾1 (at an S/N ratio of 3). The method was applied to the determination of ENR in spiked fish samples, and recoveries ranged from 68.88 to 100.29 % with relative standard deviations (for n = 3) between 1.6 and 4.4 %.}