Crystallization behavior of 70GeS2-0In2S3-0CsI chalcohalide glass with silver addition

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• 作者：Fei Huang (1) (2)
  Yinsheng Xu (1)
  Liyan Chen (1) (2)
  Qiuhua Nie (1) (2)
  Shaoqian Zhang (3)
  Shixun Dai (1)
  
• 关键词：Chalcogenide glass ; ceramics ; Activation energy ; Thermal properties ; Mechanical properties
• 刊名：Journal of Thermal Analysis and Calorimetry
• 出版年：2014
• 出版时间：September 2014
• 年：2014
• 卷：117
• 期：3
• 页码：1271-1276
• 全文大小：824 KB
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• 作者单位：Fei Huang (1) (2)
  Yinsheng Xu (1)
  Liyan Chen (1) (2)
  Qiuhua Nie (1) (2)
  Shaoqian Zhang (3)
  Shixun Dai (1)
  
  1. Laboratory of Infrared Materials and Devices, Advanced Technology Research Institute, Ningbo University, Ningbo, 315211, China
  2. College of Information Science and Engineering, Ningbo University, Ningbo, 315211, China
  3. Key Laboratory of Chemical Laser, Chinese Academy of Sciences/Dalian Institute of Chemical Physics, Dalian, 116023, China
  
• ISSN：1572-8943

文摘

The crystallization behavior of the 70GeS2-0In2S3-0CsI glass introduced with 2?mol% Ag2S system has been studied under non-isothermal condition. The beginning of transmission is shifted toward longer wavelength as a function of annealing temperature. Thermal properties were measured by the differential scanning calorimeter. From the heating rate dependence of crystallization temperature, the activation energy (E c) for crystallization and the crystallization rate constant (K) were calculated. The K value of 2.44?×?109 for the In2S3 phase is about 28 times larger than the second CP, this is why the controllable crystallization to transparent chalcogenide glass-ceramics with sole In2S3 crystallites can be achieved. By heat treatment with various temperatures, the hardness of the glass enhanced from 204 to 230.8?kg?mm?, while retained the transmittance of the 8-1?μm.