Markedly improving asymmetric oxidation of 1-(4-methoxyphenyl) ethanol with Acetobacter sp. CCTCC M209061 cells by adding deep eutectic solvent in a two-phase system

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• 作者：Ping Wei ; Jing Liang ; Jing Cheng ; Min-Hua Zong ; Wen-Yong Lou
• 关键词：Asymmetric oxidation ; Immobilized Acetobacter sp. CCTCC M209061 cells ; MOPE ; Biphasic system ; DES
• 刊名：Microbial Cell Factories
• 出版年：2016
• 出版时间：December 2016
• 年：2016
• 卷：15
• 期：1
• 全文大小：1,296 KB
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• 作者单位：Ping Wei (1) (2)
  Jing Liang (1) (3)
  Jing Cheng (1) (3)
  Min-Hua Zong (2) (3)
  Wen-Yong Lou (1) (3)
  
  1. State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou, 510640, Guangdong, People’s Republic of China
  2. School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, 510640, Guangdong, People’s Republic of China
  3. Lab of Applied Biocatalysis, College of Food Science and Engineering, South China University of Technology, Guangzhou, 510640, Guangdong, People’s Republic of China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Biotechnology
  Applied Microbiology
  Environmental Engineering/Biotechnology
  
• 出版者：BioMed Central
• ISSN：1475-2859

文摘

Background Enantiopure (S)-1-(4-methoxyphenyl) ethanol {(S)-MOPE} can be employed as an important synthon for the synthesis of cycloalkyl [b] indoles with the treatment function for general allergic response. To date, the biocatalytic resolution of racemic MOPE through asymmetric oxidation in the biphasic system has remained largely unexplored. Additionally, deep eutectic solvents (DESs), as a new class of promising green solvents, have recently gained increasing attention in biocatalysis for their excellent properties and many successful examples in biocatalytic processes. In this study, the biocatalytic asymmetric oxidation of MOPE to get (S)-MOPE using Acetobacter sp. CCTCC M209061 cells was investigated in different two-phase systems, and adding DES in a biphasic system was also explored to further improve the reaction efficiency of the biocatalytic oxidation.