Prospective application of carbon-silica derived from SiC-Si sludge as a support for Fe catalysts
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- 作者：Mi Sun Lee ; Kyun Young Park ; Hoey Kyung Park…
- 关键词：Carbon ; silica ; SiC ; Si Sludge ; Surface Area ; Fe
- 刊名：Korean Journal of Chemical Engineering
- 出版年：2017
- 出版时间：January 2017
- 年：2017
- 卷：34
- 期：1
- 页码：100-104
- 全文大小：
- 刊物类别：Chemistry and Materials Science
- 刊物主题：Industrial Chemistry/Chemical Engineering; Catalysis; Materials Science, general; Biotechnology;
- 出版者：Springer US
- ISSN：1975-7220
- 卷排序：34
文摘
A unique carbon-silica (30 wt%) material was prepared by H2O activation at 700 °C for 8 h with the carbon derived from SiC-Si sludge and the in-situ hydrolysis of the SiCl4 trapped in the pores of the carbon into silica. The BET surface area of the carbon-silica was 1,750 m2/g and the pore volume by QSDFT was 1.13 cm3/g, 40% of which stemmed from micropores smaller than 2 nm with 60% from mesopores between 2 nm and 50 nm. The activated carbon-silica was loaded with Fe by means of chemical vapor infiltration (CVI) and incipient wetness impregnation (IWI). A hydrogen temperature-programmed reduction test showed that the activated carbon-silica is a prospective support material for Fe catalysts and that the dispersion of Fe in the carbon-silica is higher with CVI than with IWI.