Hydrothermal synthesis, structures and properties of metal phosphonates based on m-xylylenediphosphonic acid
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- 作者：Yu Yang (1)
Wei Xu (1)
Yuanxin Li (1)
Meng Liu (1)
Yiheng Zhang (1)
Lei Wang (1) - 关键词：Metal phosphonate ; Open framework ; Hydrothermal synthesis ; Structural characterization
- 刊名：Chinese Science Bulletin
- 出版年：2014
- 出版时间：December 2014
- 年：2014
- 卷：59
- 期：34
- 页码：4720-4727
- 全文大小：1,801 KB
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16. Yi XY, Zheng LM, Xu W et al (2003) Nov - 作者单位：Yu Yang (1)
Wei Xu (1)
Yuanxin Li (1)
Meng Liu (1)
Yiheng Zhang (1)
Lei Wang (1)
1. Key Laboratory of Eco-chemical Engineering, Ministry of Education, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, 266042, China - ISSN：1861-9541
文摘
In this work, a series of new metal phosphonates were hydrothermally synthesized and structurally characterized based on m-xylylenediphosphonic acids (H4L), including [M(H2L)(bpy)] (M?=?Mn 1, Co 2), [MH2L)(phen)] (M?=?Co 3, Cu 4), and [Cu2(H2L)2(bpy-2] 5 (bpy?=?2,2-bipyridine, phen?=?1,10-phenanthroline, bpy″??4,4-dimethyl-2,2-bipyridine). X-ray diffraction indicated that compounds 1 and 2 were isomorphic. Complexes 3 and 4 were shown to crystallize in different space groups but had similar crystallographic units. In the complexes, H4L was seen to partially deprotonate to afford H2L2?/sup>. The H2L2?/sup> ligands in 1-strong class="a-plus-plus">4 functioned as tetradentate ligands with each phosphonate group adopting bidentate coordination mode with two M centers to generate a 2D layer. In addition, the H2L2?/sup> anions in 5 functioned as tridentate ligands with one phosphonate group adopting the bidentate mode and another phosphonate group adopti ng the monodentate mode, thus linking three Cu atoms to provide a 1D chain. The IR and thermal stabilities of these compounds were subsequently examined.