Two Energetic Cobalt(II) Coordination Polymers Derived from Isomeric Ligands

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• 作者：Da Liang Zhu ; Qiu Yan Yue ; Jue Wang…
• 关键词：Co(II) ; Isomer ; Crystal structure ; Energetic material
• 刊名：Journal of Inorganic and Organometallic Polymers and Materials
• 出版年：2016
• 出版时间：May 2016
• 年：2016
• 卷：26
• 期：3
• 页码：616-622
• 全文大小：1,788 KB
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• 作者单位：Da Liang Zhu (1)
  Qiu Yan Yue (1)
  Jue Wang (1)
  Meng Yue Guo (1)
  Li Li Miao (1)
  Li Jun Qiu (1)
  Qiao Yun Li (1)
  Gao Wen Yang (1)
  
  1. Jiangsu Laboratory of Advanced Functional Material, Department of Chemistry and Material Engineering, Changshu Institute of Technology, Changshu, 215500, Jiangsu, People’s Republic of China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Inorganic Chemistry
  Organic Chemistry
  Polymer Sciences
  
• 出版者：Springer New York
• ISSN：1574-1451

文摘

Isomer is sometimes fundamental to the formation of the resulting compounds. The design and preparation of coordination compounds based on isomers is of tremendous paramount since they have a lot in common but simultaneously some difference, which can lead to variation of both the topologies and properties. Solvothermal reactions of Hn-pytza (n = 3, 4) with Co(ClO₄)₂·6H₂O, afforded two interesting coordination polymers, one dimensional [Co(3-pytza)₂(H₂O)₂]_n·2nH₂O (1) and three dimensional [Co(4-pytza)₂]_n (2), where Hn-pytza = 5-(n-pyridyl)tetrazole-2-acetic acid (n = 3, 4). The thermal decomposition behavior of the two compounds were characterized by the differential scanning calorimetry (DSC) and thermogravimetric-differential thermogravimetric (TG-DTG), showing [Co(4-pytza)₂]_n is superior to [Co(3-pytza)₂(H₂O)₂]_n·2nH₂O in terms of energetic performance. Furthermore, the entropy of activation (∆S), enthalpy of activation (∆H), and free energy of activation (∆G) were calculated, as well.