Hierarchical carbon nanocages as high-rate anodes for Li- and Na-ion batteries

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• 作者：Zhiyang Lyu ; Lijun Yang ; Dan Xu ; Jin Zhao ; Hongwei Lai ; Yufei Jiang…
• 刊名：Nano Research
• 出版年：2015
• 出版时间：November 2015
• 年：2015
• 卷：8
• 期：11
• 页码：3535-3543
• 全文大小：2,024 KB
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• 作者单位：Zhiyang Lyu (1)
  Lijun Yang (1)
  Dan Xu (1)
  Jin Zhao (1)
  Hongwei Lai (1)
  Yufei Jiang (1)
  Qiang Wu (1)
  Yi Li (1)
  Xizhang Wang (1)
  Zheng Hu (1)
  
  1. Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chinese Library of Science
  Chemistry
  Nanotechnology
  
• 出版者：Tsinghua University Press, co-published with Springer-Verlag GmbH
• ISSN：1998-0000

文摘

Novel hierarchical carbon nanocages (hCNCs) are proposed as high-rate anodes for Li- and Na-ion batteries. The unique structure of the porous network for hCNCs greatly favors electrolyte penetration, ion diffusion, electron conduction, and structural stability, resulting in high rate capability and excellent cyclability. For lithium storage, the corresponding electrode stores a steady reversible capacity of 970 mAh·g−1 at a rate of 0.1 A·g−1 after 10 cycles, and stabilizes at 229 mAh·g−1 after 10,000 cycles at a high rate of 25 A·g−1 (33 s for full-charging) while delivering a large specific power of \(37 kW \cdot kg_{electrode^{ - 1} }\) and specific energy of \(339 Wh \cdot kg_{electrode^{ - 1} }\). For sodium storage, the hCNC reaches a high discharge capacity of ∼50 mAh·g−1 even at a high rate of 10 A·g−1.