Preparation and Characterization of Polysiloxane@CeO2@PMMA Hybrid Nano/Microspheres via In Situ One-Pot Process
详细信息 查看全文
- 作者：Jingang Hu (1)
Yuming Zhou (1)
Xiaoli Sheng (1) - 关键词：Polymers ; Hybrid materials ; Nanocomposites ; Functional composites
- 刊名：Journal of Inorganic and Organometallic Polymers and Materials
- 出版年：2014
- 出版时间：November 2014
- 年：2014
- 卷：24
- 期：6
- 页码：1086-1091
- 全文大小：1,343 KB
- 参考文献：1. L. Zhang, F. Li, Y. Chen, X. Wang, J. Lumin. 131, 1701 (2011) CrossRef
2. H. Althues, J. Henle, S. Kaskel, Chem. Soc. Rev. 36, 1454 (2007) CrossRef
3. M.E. Calvo, J.R. Castro Smirnov, H. Míguez, J. Polym. Sci. Pol. Phys. 50, 945 (2012) CrossRef
4. M.E. Calvo, H.N. Míguez, Chem. Mater. 22, 3909 (2010) CrossRef
5. L. Mazzocchetti, M. Scandola, A. Pollicino, Polymer 49, 5215 (2008) CrossRef
6. E. Cortecchia, L. Mazzocchetti, M. Scandola, Macromol. Chem. Phys. 210, 1834 (2009) CrossRef
7. Q. Zhang, T. Atay, J.R. Tischler, M.S. Bradley, V. Bulovic, A.V. Nurmikko, Nat. Nanotechnol. 2, 555 (2007) CrossRef
8. J. Mu, Y. Zhou, X. Bu, T. Zhang, J. Inorg. Organomet. Polym. Mater. 24, 776 (2014) CrossRef
9. H.-J. Zhang, H.-M. Xiong, Q.-G. Ren, Y.-Y. Xia, J.-L. Kong, J. Mater. Chem. 22, 13159 (2012) CrossRef
10. H.-M. Xiong, Y. Xu, Q.-G. Ren, Y.-Y. Xia, J. Am. Chem. Soc. 130, 7522 (2008) CrossRef
11. H. Zeng, G. Duan, Y. Li, S. Yang, X. Xu, W. Cai, Adv. Funct. Mater. 20, 561 (2010) CrossRef
12. H.M. Xiong, Adv. Mater. 25, 5329 (2013) CrossRef
13. C. Pisano, ?. Figiel, Compos. Sci. Technol. 75, 35 (2013) CrossRef
14. S. Bagheri-Kazemabad, D. Fox, Y. Chen, L.M. Geever, A. Khavandi, R. Bagheri, C.L. Higginbotham, H. Zhang, B. Chen, Compos. Sci. Technol. 72, 1697 (2012) CrossRef
15. W.J.E. Beek, M.M. Wienk, R.A.J. Janssen, Adv. Funct. Mater. 16, 1112 (2006) CrossRef
16. H.M. Xiong, Z.D. Wang, Y.Y. Xia, Adv. Mater. 18, 748 (2006) CrossRef
17. D.P. Liu, G.D. Li, Y. Su, J.S. Chen, Angew. Chem. Int. Ed. Engl. 45, 7370 (2006) CrossRef
18. K.W. Liu, R. Chen, G.Z. Xing, T. Wu, H.D. Sun, Appl. Phys. Lett. 96, 023111 (2010) CrossRef
19. C. Sanchez, P. Belleville, M. Popall, L. Nicole, Chem. Soc. Rev. 40, 696 (2011) CrossRef
20. M.A. Milani, D. González, R. Quijada, N.R.S. Basso, M.L. Cerrada, D.S. Azambuja, G.B. Galland, Compos. Sci. Technol. 84, 1 (2013) Hu (1)
Yuming Zhou (1)
Xiaoli Sheng (1)
1. Optoelectronic Functional Materials and Engineering Laboratory, School of Chemistry and Chemical Engineering, Southeast University, Nanjing, 211189, Jiangsu, People’s Republic of China - ISSN：1574-1451
文摘
In this study, polysiloxane@CeO2@PMMA microspheres were successfully synthesized by controllable one-pot process, in which CeO2 nanoparticles were stabilized in the surface of PMMA nano/microsphere using an in situ precipitation method. The core–shell structure of the synthesized product were confirmed by FT-IR, XRD and electronic microscope analysis. The size of polysiloxane@CeO2@PMMA nano/microspheres were about 550?nm via microscopy analysis. Moreover, the novel hybrid nanocomposites eliminated the yellowish coloration problem of CeO2 and had good dispersibility. In addition, the transmittance of the multifunctional films based on polysiloxane@CeO2@PMMA microspheres owned good transmittance of visible light and can block harmful UV rays, which can be attributed to nano-CeO2 accession. Hence, such green synthesized route can be considered as a simple common method for preparing UV-shielding multifunctional materials.