Research of fluorescent spectra of oleic acid-stabilized ZnSe nanocrystals based on UV light modification

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• 作者：Licai Hao ; Zhongchen Bai ; Zhaoliang Huang ; Sha Liao ; Zhengping Zhang
• 刊名：Applied Physics A: Materials Science & Processing
• 出版年：2016
• 出版时间：November 2016
• 年：2016
• 卷：122
• 期：11
• 全文大小：4,067 KB
• 刊物类别：Physics and Astronomy
• 刊物主题：Physics
  Condensed Matter
  Optical and Electronic Materials
  Nanotechnology
  Characterization and Evaluation Materials
  Surfaces and Interfaces and Thin Films
  Operating Procedures and Materials Treatment
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1432-0630
• 卷排序：122

文摘

The non-aqueous synthesized and post-preparative treatment of oleic acid (OA)-stabilized ZnSe nanocrystals were studied systematically. ZnSe nanocrystals were successfully synthesized via paraffin liquid and oleic acid system by using OA as stabilizer. Synthesized nanocrystals were characterized by means of absorption and fluorescent spectra, Fourier transform infrared spectrometer, transmission electron microscopy and selected area electron diffraction. Furthermore, solutions of ZnSe nanocrystals were illuminated with UV light. The experimental results showed that the fluorescent peak was red-shifted from 445 to 510 nm. The results suggested that, when the solution under illumination, OA was removed from the surface of ZnSe nanocrystals and the surface of ZnSe nanocrystals was oxidized to ZnO nanocrystals. ZnSe/ZnO core/shell nanocrystals were formed when the solution of ZnSe nanocrystals illuminated with UV light.