用户名： 密码： 验证码：
[Re6(μ3-Se)8]2+ Core-Containing Cluster Complexes with Isonicotinic Acid: Synthesis, Structural Characterization, and Hydrogen-Bo
详细信息    查看全文
  • 作者：William C. Corbin ; Gary S. Nichol ; Zhiping Zheng
  • 关键词：Rhenium chalcogenide clusters ; Deprotonation ; Coordination ; Crystal structure ; Hydrogen Bond
  • 刊名：Journal of Cluster Science
  • 出版年：2015
  • 出版时间：January 2015
  • 年：2015
  • 卷：26
  • 期：1
  • 页码：279-290
  • 全文大小：740 KB
  • 参考文献：1. S. Belin, R. Chevrel, and M. Sergent (1999). / J. Solid State Chem. 145, 159. CrossRef
    2. R. Brusetti, O. Laborde, A. Sulpice, R. Calemczuk, M. Potel, and P. Gougeon (1995). / Phys. Rev. B. 52, 4481. CrossRef
    3. J. P. Gabriel, K. Boubekeur, S. Uriel, and P. Batail (2001). / Chem. Rev. 101, 2037. CrossRef
    4. M. A. Shestopalov, Y. V. Mironov, K. A. Brylev, and V. E. Fedorov (2008). / Russ. Chem. Bull. 57, 1644. CrossRef
    5. Z. Zheng, J. R. Long, and R. H. Holm (1997). / J. Am. Chem. Soc. 119, 2163. CrossRef
    6. M. A. Shestopalov, Y. V. Mironov, K. A. Brylev, S. G. Kozlova, V. E. Fedorov, H. Spies, H.-J. Pietzsch, H. Stephan, G. Geipel, and G. Bernhard (2007). / J. Am. Chem. Soc. 129, 3714. CrossRef
    7. P. Orto, H. D. Selby, D. Ferris, J. R. Maeyer, and Z. Zheng (2007). / Inorg. Chem. 46, 4377. CrossRef
    8. Z. Zheng (2012). / Dalton Trans. 41, 5121. CrossRef
    9. X. Tu, E. Boroson, H. Truong, A. Mu?oz-Castro, R. Arratia-Pérez, G. S. Nichol, and Z. Zheng (2010). / Inorg. Chem. 49, 380. CrossRef
    10. X. Tu, H. Truong, E. Alster, A. Mu?oz-Castro, R. Arratia-Pérez, G. S. Nichol, and Z. Zheng (2011). / Chem. Eur. J. 17, 580. CrossRef
    11. S. A. Knott, J. N. Templeton, J. L. Durham, A. M. Howard, R. McDonald, and L. F. Szczepura (2013). / Dalton Trans. 42, 8132. CrossRef
    12. L. F. Szczepura, M. K. Oh, S. A. Knott (2007). / Chem. Commun. 4616.
    13. B. K. Roland, W. H. Flora, M. D. Carducci, N. R. Armstrong, and Z. Zheng (2003). / J. Cluster Sci. 14, 449. CrossRef
    14. H. D. Selby, P. Orto, and Z. Zheng (2003). / Polyhedron. 22, 2999. CrossRef
    15. V. E. Fedorov, N. G. Naumov, Y. V. Mironov, A. V. Virovets, S. B. Artemkina, K. A. Brylev, S. S. Yarovoi, O. A. Efremova, and U.-H. Peak (2002). / J. Struct. Chem 43, 669. CrossRef
    16. S. B. Artemkina, N. G. Naumov, A. V. Virovets, O. Oeckler, A. Simon, S. B. Erenburg, N. V. Bausk, V. E. Fedorov (2002). / Eur. J. Inorg. Chem.
    17. L. G. Beauvais, M. P. Shores, and J. R. Long (2000). / J. Am. Chem. Soc. 122, 2763. CrossRef
    18. M. V. Bennett, L. G. Beauvais, M. P. Shores, and J. R. Long (2001). / J. Am. Chem. Soc. 123, 8022. CrossRef
    19. K. A. Brylev, G. Pilet, N. G. Naumov, A. Perrin, V. E. Fedorov (2005). / Eur. J. Inorg. Chem. 461.
    20. S. Carlsson, L. Zorina, D. R. Allen, J. P. Attfield, E. Canadell, and P. Batail (2013). / Inorg. Chem. 52, 3326.
文摘
Three new complexes of the [Re6(μ3-Se)8]2+ core-containing cluster with isonicotinic acid (INA) were synthesized and characterized by multinuclear NMR (1H and 31P) and high-resolution mass spectrometry. Their molecular and crystal structures were determined by single-crystal X-ray diffraction studies. Unusual degrees of deprotonation of the INA ligand(s) are observed in the crystal structure, possibly due to the activation by the Lewis acidic cluster core. Extensive hydrogen bonding interactions occurring between carboxylate groups of neighboring cluster units as revealed by crystallographic studies lead to the assembly of both linear and zigzag multi-cluster chains in the solid state.

© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号

地址：北京市海淀区学院路29号 邮编：100083

电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700